Be2bo3f: a phase of beryllium fluoride borate derived from kbe2bo3f2 with short uv absorption edge
文献类型：期刊论文
| 作者 | Guo, Shu1,2; Liu, Lijuan1; Xia, Mingjun1; Kang, Lei1,2; Huang, Qian1,2; Li, Chao1,2; Wang, Xiaoyang1; Lin, Zheshuai1; Chen, Chuangtian1 |
| 刊名 | Inorganic chemistry
 |
| 出版日期 | 2016-07-04 |
| 卷号 | 55期号:13页码:6586-6591 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.6b00755 |
| 通讯作者 | Liu, lijuan(llj@mail.ipc.ac.cn) |
| 英文摘要 | A phase of beryllium fluoride borate be2bo3f (bbf) was successfully developed and grown by spontaneous nucleation from high temperature solution. the crystal belongs to the trigonal space group of r (3) over barc (no. 167), with lattice parameters a = 4.442(1) angstrom, c = 24.956(5) angstrom, and z = 2. it is constructed by the infinite planar [be2bo3f2](infinity) layers, in which the planar triangle [bo3](3-) and the tetrahedral [beo3f](5-) anionic groups are arranged in parallel via corner-sharing 0 atoms in each ab plane. bbf is an incongruent compound and decomposes at about 650 degrees c. the deep-ultraviolet (duv) transmittance spectrum reveals that its uv cutoff wavelength is down to similar to 150 nm. theoretical calculations show that bbf has a large birefringence (delta n = 0.13 at 200 nm), which mainly originates from the infinite planar [be2bo3f2](infinity) layers. in conclusion, bbf may be served as a potential duv birefringent material. |
| WOS关键词 | NONLINEAR-OPTICAL CRYSTAL ; BOND-VALENCE PARAMETERS ; ULTRAVIOLET ; DESIGN ; SOLIDS ; ENERGY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000379455900030 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374549 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Lijuan |
| 作者单位 | 1.Chinese Acad Sci, Beijing Ctr Crystal Res & Dev, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Shu,Liu, Lijuan,Xia, Mingjun,et al. Be2bo3f: a phase of beryllium fluoride borate derived from kbe2bo3f2 with short uv absorption edge[J]. Inorganic chemistry,2016,55(13):6586-6591. |
| APA | Guo, Shu.,Liu, Lijuan.,Xia, Mingjun.,Kang, Lei.,Huang, Qian.,...&Chen, Chuangtian.(2016).Be2bo3f: a phase of beryllium fluoride borate derived from kbe2bo3f2 with short uv absorption edge.Inorganic chemistry,55(13),6586-6591. |
| MLA | Guo, Shu,et al."Be2bo3f: a phase of beryllium fluoride borate derived from kbe2bo3f2 with short uv absorption edge".Inorganic chemistry 55.13(2016):6586-6591. |
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来源：中国科学院大学
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