Synthesis of hollow platinum-palladium nanospheres with a dendritic shell as efficient electrocatalysts for methanol oxidation
文献类型:期刊论文
作者 | Lu, Qingqing1,2; Wang, Hongjing3; Eid, Kamel1,2; Alothman, Zeid Abdullah4; Malgras, Victor5; Yamauchi, Yusuke5,6; Wang, Liang1,3 |
刊名 | Chemistry-an asian journal
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出版日期 | 2016-07-05 |
卷号 | 11期号:13页码:1939-1944 |
关键词 | Electrochemistry Nanoparticles Palladium Platinum Template synthesis |
ISSN号 | 1861-4728 |
DOI | 10.1002/asia.201600480 |
通讯作者 | Wang, hongjing(hjw@zjut.edu.cn) ; Wang, liang(wangliang@zjut.edu.cn) |
英文摘要 | Engineering the size, composition, and morphology of platinum-based nanomaterials can provide a great opportunity to improve the utilization efficiency of electrocatalysts and reinforce their electrochemical performances. herein, three-dimensional platinum-palladium hollow nanospheres with a dendritic shell (ptpd-hnss) are successfully fabricated through a facile and economic route, during which sio2 microspheres act as the hard template for the globular cavity, whereas the triblock copolymer f127 contributes to the formation of the dendritic shell. in contrast with platinum hollow nanospheres (pt-hnss) and commercial platinum on carbon (pt/c) catalyst, the novel architecture shows a remarkable activity and durability toward the methanol oxidation reaction (mor) owing to the coupled merits of bimetallic nanodendrites and a hollow interior. as a proof of concept, this strategy is also extended to trimetallic gold-palladium-platinum hollow nanospheres (aupdpt-hnss), which paves the way towards the controlled synthesis of other bi- or multimetallic platinum-based hollow electrocatalysts. |
WOS关键词 | OXYGEN REDUCTION REACTION ; AMPHIPHILIC TRIBLOCK COPOLYMERS ; ONE-STEP SYNTHESIS ; CATALYTIC-ACTIVITY ; FACILE SYNTHESIS ; ALLOY NANOPARTICLES ; PHASE SYNTHESIS ; ELECTROOXIDATION ; NANOCRYSTALS ; NANOWIRES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000379926000012 |
出版者 | WILEY-V C H VERLAG GMBH |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374563 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Hongjing; Wang, Liang |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Elect Chem, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 4.King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia 5.Natl Inst Mat Sci, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 6.Univ Wollongong, AIIM, North Wollongong, NSW 2500, Australia |
推荐引用方式 GB/T 7714 | Lu, Qingqing,Wang, Hongjing,Eid, Kamel,et al. Synthesis of hollow platinum-palladium nanospheres with a dendritic shell as efficient electrocatalysts for methanol oxidation[J]. Chemistry-an asian journal,2016,11(13):1939-1944. |
APA | Lu, Qingqing.,Wang, Hongjing.,Eid, Kamel.,Alothman, Zeid Abdullah.,Malgras, Victor.,...&Wang, Liang.(2016).Synthesis of hollow platinum-palladium nanospheres with a dendritic shell as efficient electrocatalysts for methanol oxidation.Chemistry-an asian journal,11(13),1939-1944. |
MLA | Lu, Qingqing,et al."Synthesis of hollow platinum-palladium nanospheres with a dendritic shell as efficient electrocatalysts for methanol oxidation".Chemistry-an asian journal 11.13(2016):1939-1944. |
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来源:中国科学院大学
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