Highly enantioselective [3+2] coupling of cyclic enamides with quinone monoimines promoted by a chiral phosphoric acid
文献类型：期刊论文
| 作者 | Zhang, Minmin1,2; Yu, Shuowen1,2; Hu, Fangzhi1,2; Liao, Yijun1,2; Liao, Lihua1,2; Xu, Xiaoying1; Yuan, Weicheng1; Zhang, Xiaomei1 |
| 刊名 | Chemical communications
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:56页码:8757-8760 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c6cc01200k |
| 通讯作者 | Zhang, xiaomei(xmzhang@cioc.ac.cn) |
| 英文摘要 | Enantioselective [3+2] coupling of cyclic enamides with quinone monoimines was realised using a chiral phosphoric acid as a catalyst. this transformation allowed for the synthesis of highly enantio-enriched polycyclic 2,3-dihydrobenzofurans (up to 99.9% ee). the absolute configuration of one product was determined by an x-ray crystal structural analysis. we also found a possible mechanism for this reaction. |
| WOS关键词 | DIELS-ALDER REACTION ; BOND-FORMING REACTIONS ; ALPHA-ARYLATION ; IMINE KETALS ; DEAROMATIZATION ; 1,4-NAPHTHOQUINONES ; (-)-GALANTHAMINE ; STRATEGIES ; OXINDOLES ; CATALYSIS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000379484200028 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374590 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Xiaomei |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chiraltechnol Sichuan Pr, Chengdu, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Minmin,Yu, Shuowen,Hu, Fangzhi,et al. Highly enantioselective [3+2] coupling of cyclic enamides with quinone monoimines promoted by a chiral phosphoric acid[J]. Chemical communications,2016,52(56):8757-8760. |
| APA | Zhang, Minmin.,Yu, Shuowen.,Hu, Fangzhi.,Liao, Yijun.,Liao, Lihua.,...&Zhang, Xiaomei.(2016).Highly enantioselective [3+2] coupling of cyclic enamides with quinone monoimines promoted by a chiral phosphoric acid.Chemical communications,52(56),8757-8760. |
| MLA | Zhang, Minmin,et al."Highly enantioselective [3+2] coupling of cyclic enamides with quinone monoimines promoted by a chiral phosphoric acid".Chemical communications 52.56(2016):8757-8760. |
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来源：中国科学院大学
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