A new strategy to microporous polypyrrole networks based on condensation of pyrrole and diketone
文献类型：期刊论文
| 作者 | Melhi, Saad1,2; Ding, Xuesong1; Liu, Zhi-Wei1; Cao, Cong-Xiao1; Han, Bao-Hang1 |
| 刊名 | Macromolecular chemistry and physics
 |
| 出版日期 | 2016-07-01 |
| 卷号 | 217期号:13页码:1529-1533 |
| 关键词 | Carbon dioxide uptake Condensation reaction Porous organic polymers Pyrrole Diketone |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.201600119 |
| 通讯作者 | Han, bao-hang(hanbh@nanoctr.cn) |
| 英文摘要 | A new synthesis route to novel porous organic polymers is reported based on condensation of pyrrole and diketone in the presence of an acid. the structure of obtained polymer is confirmed by fourier transform infrared and solid-state c-13 nuclear magnetic resonance spectroscopy. the resulting polypyrrole network with high brunauer-emmet-teller specific surface area over 650 m(2) g(-1), possesses gas uptake capacities, that is, hydrogen (0.70 wt% at 77 k), carbon dioxide (8.5 wt% at 273 k), and methane (0.95 wt% at 273 k) at 1.0 bar. the facile preparation strategy on the basis of condensation of pyrrole and diketone will provide an avenue to prepare porous organic polymers. |
| WOS关键词 | POROUS ORGANIC POLYMERS ; GAS-STORAGE ; CO2 CAPTURE ; ANION-BINDING ; SURFACE-AREA ; DOPED CARBON ; SELECTIVITY ; SEPARATION ; FRAMEWORKS ; CALIXPYRROLES |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000380017700012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374605 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Han, Bao-Hang |
| 作者单位 | 1.Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Melhi, Saad,Ding, Xuesong,Liu, Zhi-Wei,et al. A new strategy to microporous polypyrrole networks based on condensation of pyrrole and diketone[J]. Macromolecular chemistry and physics,2016,217(13):1529-1533. |
| APA | Melhi, Saad,Ding, Xuesong,Liu, Zhi-Wei,Cao, Cong-Xiao,&Han, Bao-Hang.(2016).A new strategy to microporous polypyrrole networks based on condensation of pyrrole and diketone.Macromolecular chemistry and physics,217(13),1529-1533. |
| MLA | Melhi, Saad,et al."A new strategy to microporous polypyrrole networks based on condensation of pyrrole and diketone".Macromolecular chemistry and physics 217.13(2016):1529-1533. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。