Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent
文献类型：期刊论文
| 作者 | Zhang, Miao1,2; Liu, Lin1; He, Teng1; Wu, Guotao1; Chen, Ping1 |
| 刊名 | Chemistry-an asian journal
 |
| 出版日期 | 2016-06-21 |
| 卷号 | 11期号:12页码:1849-1855 |
| 关键词 | 2d carbonaceous polymer nanosheets Carbon dioxide capture Ionothermal method Microporous materials Polymers |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201600396 |
| 通讯作者 | Liu, lin(liulin@dicp.ac.cn) ; Chen, ping(pchen@dicp.ac.cn) |
| 英文摘要 | The synthesis of two-dimensional (2d) polymer nanosheets with a well-defined microporous structure remains challenging in materials science. here, a new kind of 2d microporous carbonaceous polymer nanosheets was synthesized through polymerization of a very low concentration of 1,4-dicyanobenzene in molten zinc chloride at 400-500 degrees c. this type of nanosheets has a thickness in the range of 3-20nm, well-defined microporosity, a high surface area (approximate to 537m(2)g(-1)), and a large micropore volume (approximate to 0.45cm(3)g(-1)). the microporous carbonaceous polymer nanosheets exhibit superior co2 sorption capability (8.14wt% at 298k and 1bar) and a relatively high co2 selectivity toward n-2 (25.6). starting from different aromatic nitrile monomers, a variety of 2d carbonaceous polymer nanosheets can be obtained showing a certain universality of the ionothermal method reported herein. |
| WOS关键词 | COVALENT ORGANIC FRAMEWORKS ; TRIAZINE-BASED FRAMEWORKS ; ON-SURFACE SYNTHESIS ; IONOTHERMAL SYNTHESIS ; DIOXIDE CAPTURE ; THIN-FILMS ; AIR/WATER INTERFACE ; LARGE-AREA ; GRAPHENE ; CAPACITY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000379519400016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374692 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Lin; Chen, Ping |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Miao,Liu, Lin,He, Teng,et al. Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent[J]. Chemistry-an asian journal,2016,11(12):1849-1855. |
| APA | Zhang, Miao,Liu, Lin,He, Teng,Wu, Guotao,&Chen, Ping.(2016).Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent.Chemistry-an asian journal,11(12),1849-1855. |
| MLA | Zhang, Miao,et al."Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent".Chemistry-an asian journal 11.12(2016):1849-1855. |
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来源：中国科学院大学
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