中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes

文献类型:期刊论文

作者Du, Cheng-Feng1,2; Shen, Nan-Nan1,2; Li, Jian-Rong1; Hao, Min-Ting1,3; Wang, Zi4; Huang, Xiao-Ying1
刊名Chemistry-an asian journal
出版日期2016-05-20
卷号11期号:10页码:1555-1564
关键词Cations Ionic liquids Open frameworks Selenium Tin
ISSN号1861-4728
DOI10.1002/asia.201600073
通讯作者Huang, xiao-ying(xyhuang@fjirsm.ac.cn)
英文摘要Presented are the ionothermal syntheses, characterizations, and properties of a series of two-and three-dimensional selenidostannate compounds synergistically directed by metal-amine complex (mac) cations and ionic liquids (ils) of [bmmim]cl (bmmim = 1-butyl-2,3-dimethyl-imidazolium). four selenidostannates, namely, 2d-(bmmim)(3)[ni(en)(3)](2)[sn9se21]cl (1, en = ethylenediamine), 2d-(bmmim)(8)[ni-2(teta)(2)(mu-teta)]sn18se42 (2, teta = triethylenetetramine), 2d-(bmmim)(4)[ni(tepa)cl](2)[ni(tepa)sn12se28] (3, tepa= tetraethylenepentamine), and 3d-(bmmim)(2)[ni(1,2-pda)(3)]sn8se18 (4, 1,2-pda = 1,2-diaminopropane), were obtained. single-crystal x-ray diffraction analyses revealed that compounds 1 and 2 possess a lamellar anionic [sn3se7](n)(2n-) structure comprising distinct eight-membered ring units, whereas 3 features a mac-decorated anionic [ni(tepa)sn12se28](n)(6n-) layered structure. in contrast to 1-3, compound 4 exhibits a 3d open framework of anionic [sn4se9](n)(2n-). the structural variation from 1 to 4 clearly indicates that on the basis of the synergistic structure-directing ability of the macs and ils, variation of the organic polyamine ligand has a significant impact on the formation of selenidostannates.
WOS关键词SOLVOTHERMAL SYNTHESIS ; IONOTHERMAL SYNTHESIS ; OPEN-FRAMEWORK ; ANION ; NETWORKS ; CLUSTERS ; TIN ; THIOANTIMONATES(III) ; TRANSFORMATION ; FLEXIBILITY
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000379518200011
出版者WILEY-V C H VERLAG GMBH
URI标识http://www.irgrid.ac.cn/handle/1471x/2374698
专题中国科学院大学
通讯作者Huang, Xiao-Ying
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350002, Fujian, Peoples R China
4.Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China
推荐引用方式
GB/T 7714
Du, Cheng-Feng,Shen, Nan-Nan,Li, Jian-Rong,et al. Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes[J]. Chemistry-an asian journal,2016,11(10):1555-1564.
APA Du, Cheng-Feng,Shen, Nan-Nan,Li, Jian-Rong,Hao, Min-Ting,Wang, Zi,&Huang, Xiao-Ying.(2016).Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes.Chemistry-an asian journal,11(10),1555-1564.
MLA Du, Cheng-Feng,et al."Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes".Chemistry-an asian journal 11.10(2016):1555-1564.

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来源:中国科学院大学

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