Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes
文献类型：期刊论文
| 作者 | Du, Cheng-Feng1,2; Shen, Nan-Nan1,2; Li, Jian-Rong1; Hao, Min-Ting1,3; Wang, Zi4; Huang, Xiao-Ying1 |
| 刊名 | Chemistry-an asian journal
 |
| 出版日期 | 2016-05-20 |
| 卷号 | 11期号:10页码:1555-1564 |
| 关键词 | Cations Ionic liquids Open frameworks Selenium Tin |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201600073 |
| 通讯作者 | Huang, xiao-ying(xyhuang@fjirsm.ac.cn) |
| 英文摘要 | Presented are the ionothermal syntheses, characterizations, and properties of a series of two-and three-dimensional selenidostannate compounds synergistically directed by metal-amine complex (mac) cations and ionic liquids (ils) of [bmmim]cl (bmmim = 1-butyl-2,3-dimethyl-imidazolium). four selenidostannates, namely, 2d-(bmmim)(3)[ni(en)(3)](2)[sn9se21]cl (1, en = ethylenediamine), 2d-(bmmim)(8)[ni-2(teta)(2)(mu-teta)]sn18se42 (2, teta = triethylenetetramine), 2d-(bmmim)(4)[ni(tepa)cl](2)[ni(tepa)sn12se28] (3, tepa= tetraethylenepentamine), and 3d-(bmmim)(2)[ni(1,2-pda)(3)]sn8se18 (4, 1,2-pda = 1,2-diaminopropane), were obtained. single-crystal x-ray diffraction analyses revealed that compounds 1 and 2 possess a lamellar anionic [sn3se7](n)(2n-) structure comprising distinct eight-membered ring units, whereas 3 features a mac-decorated anionic [ni(tepa)sn12se28](n)(6n-) layered structure. in contrast to 1-3, compound 4 exhibits a 3d open framework of anionic [sn4se9](n)(2n-). the structural variation from 1 to 4 clearly indicates that on the basis of the synergistic structure-directing ability of the macs and ils, variation of the organic polyamine ligand has a significant impact on the formation of selenidostannates. |
| WOS关键词 | SOLVOTHERMAL SYNTHESIS ; IONOTHERMAL SYNTHESIS ; OPEN-FRAMEWORK ; ANION ; NETWORKS ; CLUSTERS ; TIN ; THIOANTIMONATES(III) ; TRANSFORMATION ; FLEXIBILITY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000379518200011 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374698 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Huang, Xiao-Ying |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350002, Fujian, Peoples R China 4.Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Cheng-Feng,Shen, Nan-Nan,Li, Jian-Rong,et al. Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes[J]. Chemistry-an asian journal,2016,11(10):1555-1564. |
| APA | Du, Cheng-Feng,Shen, Nan-Nan,Li, Jian-Rong,Hao, Min-Ting,Wang, Zi,&Huang, Xiao-Ying.(2016).Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes.Chemistry-an asian journal,11(10),1555-1564. |
| MLA | Du, Cheng-Feng,et al."Synthesizing 2d and 3d selenidostannates in ionic liquids: the synergistic structure-directing effects of ionic liquids and metal-amine complexes".Chemistry-an asian journal 11.10(2016):1555-1564. |
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来源：中国科学院大学
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