Visible light-driven photocatalytic heck reaction over carbon nanocoil supported pd nanoparticles
文献类型：期刊论文
| 作者 | Guo, Xiao-Wei1; Hao, Cai-Hong2,4; Wang, Cheng-Yu1; Sarina, Sarina3; Guo, Xiao-Ning2; Guo, Xiang-Yun2 |
| 刊名 | Catalysis science & technology
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:21页码:7738-7743 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c6cy01322h |
| 通讯作者 | Wang, cheng-yu(wangcy@nefu.edu.cn) ; Sarina, sarina(s.sarina@qut.edu.au) ; Guo, xiao-ning(guoxiaoning@sxicc.ac.cn) |
| 英文摘要 | Pd nanoparticles supported on carbon nanocoils (pd/cncs) show unexpectedly high photocatalytic activity for coupling reaction of aryl halides and alkenes (heck reaction) at 40 degrees c. the energetic electrons in pd nanoparticles, excited via interband transitions under visible light irradiation, can transfer to halogen atoms to facilitate the cleavage of carbon-halogen bonds in aryl halides, which requires rather high temperature in the thermal process. then, the final products can be fast achieved by alkene insertion and beta-hydrogen elimination processes. |
| WOS关键词 | COUPLING REACTIONS ; METAL NANOPARTICLES ; ORGANIC-SYNTHESIS ; TITANIUM-DIOXIDE ; LAYER DEPOSITION ; PALLADIUM ; IRRADIATION ; NANOSTRUCTURES ; MECHANISM ; CATALYSTS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000386424200010 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375003 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Cheng-Yu; Sarina, Sarina; Guo, Xiao-Ning |
| 作者单位 | 1.Northeast Forestry Univ, Minist Educ, Key Lab Biobased Mat Sci & Technol, Harbin 150040, Peoples R China 2.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 3.Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia 4.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xiao-Wei,Hao, Cai-Hong,Wang, Cheng-Yu,et al. Visible light-driven photocatalytic heck reaction over carbon nanocoil supported pd nanoparticles[J]. Catalysis science & technology,2016,6(21):7738-7743. |
| APA | Guo, Xiao-Wei,Hao, Cai-Hong,Wang, Cheng-Yu,Sarina, Sarina,Guo, Xiao-Ning,&Guo, Xiang-Yun.(2016).Visible light-driven photocatalytic heck reaction over carbon nanocoil supported pd nanoparticles.Catalysis science & technology,6(21),7738-7743. |
| MLA | Guo, Xiao-Wei,et al."Visible light-driven photocatalytic heck reaction over carbon nanocoil supported pd nanoparticles".Catalysis science & technology 6.21(2016):7738-7743. |
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来源：中国科学院大学
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