Domino radical addition/oxidation sequence with photocatalysis: one-pot synthesis of polysubstituted furans from alpha-chloro-alkyl ketones and styrenes
文献类型：期刊论文
| 作者 | Wang, Shuang1; Jia, Wen-Liang1; Wang, Lin1; Liu, Qiang1; Wu, Li-Zhu2 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 22期号:39页码:13794-13798 |
| 关键词 | Domino reaction Furans Photocatalysis Radical reactions Styrenes |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201602053 |
| 通讯作者 | Liu, qiang(liuqiang@lzu.edu.cn) ; Wu, li-zhu(lzwu@mail.ipc.ac.cn) |
| 英文摘要 | A new domino reaction has been developed that allows the combination of styrenes and alpha-alkyl ketone radicals to afford a wide array of polysubstituted furans in good to excellent yields under mild and simple reaction conditions. the key to success of this novel protocol is the use of photocatalyst fac-ir(ppy)(3) and oxidant k2s2o8. mechanistic studies by a radical scavenger and photoluminescence quenching suggest that a radical addition/oxidation pathway is operable. |
| WOS关键词 | LIGHT PHOTOREDOX CATALYSIS ; HIGHLY SUBSTITUTED FURANS ; VISIBLE-LIGHT ; PHENANTHRIDINE DERIVATIVES ; ORGANIC-SYNTHESIS ; REGIOSELECTIVE SYNTHESIS ; MULTISUBSTITUTED FURANS ; ALLENYL KETONES ; GAMMA-LACTONES ; CYCLIZATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000384694700011 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375026 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Qiang; Wu, Li-Zhu |
| 作者单位 | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Univ Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Shuang,Jia, Wen-Liang,Wang, Lin,et al. Domino radical addition/oxidation sequence with photocatalysis: one-pot synthesis of polysubstituted furans from alpha-chloro-alkyl ketones and styrenes[J]. Chemistry-a european journal,2016,22(39):13794-13798. |
| APA | Wang, Shuang,Jia, Wen-Liang,Wang, Lin,Liu, Qiang,&Wu, Li-Zhu.(2016).Domino radical addition/oxidation sequence with photocatalysis: one-pot synthesis of polysubstituted furans from alpha-chloro-alkyl ketones and styrenes.Chemistry-a european journal,22(39),13794-13798. |
| MLA | Wang, Shuang,et al."Domino radical addition/oxidation sequence with photocatalysis: one-pot synthesis of polysubstituted furans from alpha-chloro-alkyl ketones and styrenes".Chemistry-a european journal 22.39(2016):13794-13798. |
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来源：中国科学院大学
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