Electrogenerated chemiluminescence of tris(2,2'-bipyridine)ruthenium(ii) using n-(3-aminopropyl)diethanolamine as coreactant
文献类型：期刊论文
| 作者 | Kitte, Shimeles Addisu1,2; Wang, Chao1,3; Li, Suping1; Zholudov, Yuriy1; Qi, Liming1,2; Li, Jianping3; Xu, Guobao1,2,3 |
| 刊名 | Analytical and bioanalytical chemistry
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 408期号:25页码:7059-7065 |
| 关键词 | Tris(2,2 '-bipyridyl)ruthenium(ii) Electrochemiluminescence Coreactant N-(3-aminopropyl)diethanolamine Primary amine group |
| ISSN号 | 1618-2642 |
| DOI | 10.1007/s00216-016-9409-z |
| 通讯作者 | Xu, guobao(guobaoxu@ciac.ac.cn) |
| 英文摘要 | Coreactant plays a critical role for the application of electrochemiluminescence (ecl). herein, n-(3-aminopropyl)diethanolamine (apdea) has been explored as a potential coreactant for enhancing tris(2,2'-bipyridyl)ruthenium(ii) ecl. it is much more effective than tripropylamine at gold and platinum electrodes although it has one primary amine group besides a tertiary amine group. the presence of primary amine group and hydroxyl groups in apdea promotes the oxidation rates of amine and thus remarkably increases ecl intensity. the ecl intensities of the ru(bpy)(3) (2+)/apdea system are approximately 10 and 36 times stronger than that of ru(bpy)(3) (2+)/tripropylamine system and about 1.6 and 1.14 times stronger than that of ru(bpy)(3) (2+)/n-butyldiethanolamine system at au and pt electrodes, respectively. the ecl intensity of the ru(bpy)(3) (2+)/apdea system is 2.42 times stronger than that of ru(bpy)(3) (2+)/n-butyldiethanolamine at glassy carbon electrodes. |
| WOS关键词 | ALIPHATIC-AMINES ; ELECTROCHEMICAL OXIDATION ; SILICA NANOPARTICLES ; CO-REACTANT ; ELECTROCHEMILUMINESCENCE ; SYSTEM ; ECL |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS类目 | Biochemical Research Methods ; Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000383704200013 |
| 出版者 | SPRINGER HEIDELBERG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375053 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Guobao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Chinese Acad Sci, 19A Yuquanlu, Beijing 100049, Peoples R China 3.Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kitte, Shimeles Addisu,Wang, Chao,Li, Suping,et al. Electrogenerated chemiluminescence of tris(2,2'-bipyridine)ruthenium(ii) using n-(3-aminopropyl)diethanolamine as coreactant[J]. Analytical and bioanalytical chemistry,2016,408(25):7059-7065. |
| APA | Kitte, Shimeles Addisu.,Wang, Chao.,Li, Suping.,Zholudov, Yuriy.,Qi, Liming.,...&Xu, Guobao.(2016).Electrogenerated chemiluminescence of tris(2,2'-bipyridine)ruthenium(ii) using n-(3-aminopropyl)diethanolamine as coreactant.Analytical and bioanalytical chemistry,408(25),7059-7065. |
| MLA | Kitte, Shimeles Addisu,et al."Electrogenerated chemiluminescence of tris(2,2'-bipyridine)ruthenium(ii) using n-(3-aminopropyl)diethanolamine as coreactant".Analytical and bioanalytical chemistry 408.25(2016):7059-7065. |
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来源：中国科学院大学
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