Synthesis and in-situ functionalization of graphene films through graphite charging in aqueous fe-2(so4)(3)
文献类型：期刊论文
| 作者 | Yan, Rui1,2; Wang, Kai1,2; Wang, Congwei1; Zhang, Huinian1,2; Song, Yan1; Guo, Quangui1; Wang, Junzhong1 |
| 刊名 | Carbon
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 107页码:379-387 |
| ISSN号 | 0008-6223 |
| DOI | 10.1016/j.carbon.2016.06.018 |
| 通讯作者 | Guo, quangui(qgguo@sxicc.ac.cn) ; Wang, junzhong(wangjz@sxicc.ac.cn) |
| 英文摘要 | Low-cost synthesis and functionization of graphene is important for its application. here, graphene and fe3o4/graphene films were both prepared via a green approach of electrochemical exfoliation of graphite paper in aqueous fe-2(so4)(3). iron ions in the electrolyte could facilitate graphite exfoliation and reduce hydrogen evolution in water medium as well as in-situ functionization of graphene. small size (4-6 nm) of fe3o4 uniformly grown onto graphene improved magnetic and electromagnetic properties as well as electrocatalytic activity of oxygen reduction reaction but decreased thermal conductivity and mechanical strength over free graphene. the films of 50 mu m thickness of fe(3)o(4)z/graphene (21-58 wt% fe3o4) exhibited excellent electromagnetic shielding of 41-62 db at 1.0-18 ghz and good thermal conductivity (120 w/(m.k)), which may be related to their high electrical conductivity (500 s/cm) and ferromagnetism (241 oe). free-standing graphene films could reach high thermal conductivity of similar to 787 w/(m.k) and electromagnetic shielding of 39-65 db at 1.0-18 ghz as well as 48 mpa mechanical strength. such competitive high performance of multi-functional graphene-based films holds a great potential in practical application. (c) 2016 published by elsevier ltd. |
| WOS关键词 | MAGNETIC FE3O4 NANOPARTICLES ; OXYGEN REDUCTION REACTION ; REDUCED GRAPHENE ; ELECTROCHEMICAL EXPANSION ; THERMAL-PROPERTIES ; RATE CAPABILITY ; OXIDE-FILMS ; HIGH-YIELD ; NANOSHEETS ; SUPERCAPACITORS |
| WOS研究方向 | Chemistry ; Materials Science |
| WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000380803600046 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375090 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Guo, Quangui; Wang, Junzhong |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Rui,Wang, Kai,Wang, Congwei,et al. Synthesis and in-situ functionalization of graphene films through graphite charging in aqueous fe-2(so4)(3)[J]. Carbon,2016,107:379-387. |
| APA | Yan, Rui.,Wang, Kai.,Wang, Congwei.,Zhang, Huinian.,Song, Yan.,...&Wang, Junzhong.(2016).Synthesis and in-situ functionalization of graphene films through graphite charging in aqueous fe-2(so4)(3).Carbon,107,379-387. |
| MLA | Yan, Rui,et al."Synthesis and in-situ functionalization of graphene films through graphite charging in aqueous fe-2(so4)(3)".Carbon 107(2016):379-387. |
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来源：中国科学院大学
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