Cellulose nanosheets induced by mechanical impacts under hydrophobic environment
文献类型：期刊论文
| 作者 | Zhao, Mengmeng1,2; Kuga, Shigenori1; Jiang, Shidong1; Wu, Min1; Huang, Yong1 |
| 刊名 | Cellulose
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 23期号:5页码:2809-2818 |
| 关键词 | Cellulose nanosheet Ball mill Elementary fibril Hydrophobic interaction |
| ISSN号 | 0969-0239 |
| DOI | 10.1007/s10570-016-1033-8 |
| 通讯作者 | Wu, min(wumin@mail.ipc.ac.cn) ; Huang, yong(yhuang@mail.ipc.ac.cn) |
| 英文摘要 | The nanoscale structural changes of crystalline cellulose by mechanical milling was studied by high-resolution microscopy (afm, sem, tem). we examined influence of environment [dry, water, silicone oil (pdms)] on cellulose milling, finding their characteristic effects on microscopic morphology of the products. dry milling of cellulose gave aggregated globular particles with fast decrystallization. milling with water or pdms caused partial dispersion of nanofibers. milling with pdms formed micro-platelets < 1 a mu m thick with slight decrystallization. remarkably, nanoscale particles isolated from pdms-milled cellulose by sonication in ethanol contained cellulose nanosheets, typically 0.1-10 a mu m wide and 4.2 nm thick, apparently formed by monolayer association of elementary fibrils. tem and electron diffraction revealed crystalline nature of nanosheets, with specific orientation of (110) plane or (200) plane perpendicular to the sheet plane. a possible mechanism of the nanosheets formation is proposed, in which the elementary fibrils are aligned parallel by mechanical impacts. |
| WOS关键词 | I-BETA ; CRYSTALLINE CELLULOSE ; MOLECULAR-DYNAMICS ; BINDING MODULES ; VISUALIZATION ; MICROFIBRIL ; SURFACES ; TWIST |
| WOS研究方向 | Materials Science ; Polymer Science |
| WOS类目 | Materials Science, Paper & Wood ; Materials Science, Textiles ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000382634300003 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375253 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Min; Huang, Yong |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, 29 Zhongguancun East Rd, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Mengmeng,Kuga, Shigenori,Jiang, Shidong,et al. Cellulose nanosheets induced by mechanical impacts under hydrophobic environment[J]. Cellulose,2016,23(5):2809-2818. |
| APA | Zhao, Mengmeng,Kuga, Shigenori,Jiang, Shidong,Wu, Min,&Huang, Yong.(2016).Cellulose nanosheets induced by mechanical impacts under hydrophobic environment.Cellulose,23(5),2809-2818. |
| MLA | Zhao, Mengmeng,et al."Cellulose nanosheets induced by mechanical impacts under hydrophobic environment".Cellulose 23.5(2016):2809-2818. |
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来源：中国科学院大学
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