Novel hydrophilic-hydrophobic block copolymer based on cardo poly (arylene ether sulfone)s with bis-quaternary ammonium moieties for anion exchange membranes
文献类型：期刊论文
| 作者 | Dong, Xue1,2; Hou, Shuhua1; Mao, Hongchao1; Zheng, Jifu1; Zhang, Suobo1,3 |
| 刊名 | Journal of membrane science
 |
| 出版日期 | 2016-11-15 |
| 卷号 | 518页码:31-39 |
| ISSN号 | 0376-7388 |
| 关键词 | Block Bis-quaternary ammonium Poly(aryl ether sulfone)s |
| DOI | 10.1016/j.memsci.2016.06.036 |
| 通讯作者 | Zheng, jifu(jfzheng@ciac.ac.cn) |
| 英文摘要 | Two types of phenolphthalein-based copolymers, random and block cardo poly(aryl ether sulfone)s with pendant tertiary amine groups were synthesized via copolycondensation. both of the copolymers were grafted with (3-bromopropyl) trimethylammonium bromide to prepare anion exchange membranes with bis-quaternary ammonium groups for hydroxide ion conductivity measurements. the block anion exchange membrane qbpes-60 with an ion exchange capacity (iec) of 1.93 mmol g(-1) exhibited higher ionic conductivity (40.5 ms cm(-1)) in water at 60 degrees c than the random copolymer qrpes-60 (30.0 ms cm(-1)) under the same conditions. small-angle x-ray scattering and transmission electron microscopy suggested the membrane constructed from the block polymer exhibited a more obvious phase-separated structure and formed ion clusters which would be responsible for the high conductivity. moreover, the block anion exchange membrane with bis-quaternary ammonium groups showed better alkaline stability than the random membrane where degradation could be recognized by 1h nmr spectra as well as ion conductivities. in conclusion, integrating the block hydrophilic bis-quaternary ammonium ion groups along with the long aliphatic side chains, and the hydrophobic copolymer backbone, this synthetic strategy is promising to prepare aems with high conductivity and good alkaline stability. (c) 2016 elsevier b.v. all rights reserved. |
| WOS关键词 | ALKALINE FUEL-CELL ; POLY(ARYLENE ETHER)S ; IMIDAZOLIUM ; STABILITY ; IONOMERS ; CATIONS |
| WOS研究方向 | Engineering ; Polymer Science |
| WOS类目 | Engineering, Chemical ; Polymer Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000382254500004 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375270 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zheng, Jifu |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, 5625 Renmin St, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 1000, Peoples R China 3.Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, Nanjing, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Xue,Hou, Shuhua,Mao, Hongchao,et al. Novel hydrophilic-hydrophobic block copolymer based on cardo poly (arylene ether sulfone)s with bis-quaternary ammonium moieties for anion exchange membranes[J]. Journal of membrane science,2016,518:31-39. |
| APA | Dong, Xue,Hou, Shuhua,Mao, Hongchao,Zheng, Jifu,&Zhang, Suobo.(2016).Novel hydrophilic-hydrophobic block copolymer based on cardo poly (arylene ether sulfone)s with bis-quaternary ammonium moieties for anion exchange membranes.Journal of membrane science,518,31-39. |
| MLA | Dong, Xue,et al."Novel hydrophilic-hydrophobic block copolymer based on cardo poly (arylene ether sulfone)s with bis-quaternary ammonium moieties for anion exchange membranes".Journal of membrane science 518(2016):31-39. |
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来源：中国科学院大学
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