Influence of a long-side-chain-containing reactive diluent on the structure and mechanical properties of uv-cured films
文献类型：期刊论文
| 作者 | Shen, Lu1,2; Wang, Ying1,2; Zhao, Qiang1,2; Luo, Fubin1,2; Chen, Junhua1,2; Lu, Mangeng1; Liang, Liyan1; Wu, Kun1; Shi, Jun1 |
| 刊名 | Polymer international
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 65期号:10页码:1150-1156 |
| 关键词 | Reactive diluent Uv curable Crosslinking Epoxy acrylate |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.5163 |
| 通讯作者 | Wu, kun(wukun@gic.ac.cn) |
| 英文摘要 | The dimethacrylate reactive diluent (hema-ddsa), a long-side-chain-containing reactive diluent, was prepared by reacting 2-dodecen-1-ylsuccinic anhydride with two equivalents of hydroxyethyl methacrylate. its structure was characterized by ir and h-1 nmr spectroscopy. this new diluent was added into the formulation of uv-curable epoxy acrylate networks. results show that the formulation with the addition of hema-ddsa has massively reduced viscosity and shows several attractive properties of epoxy acrylate oligomers. the mechanical resistance of the films is dramatically enhanced with the incorporation of long alkyl groups derived from hema-ddsa, the plastic deformation zone expands, thus decreasing the inner stress of the polymer structure. moreover, the cured coatings have a higher glass transition temperature as the percentage of hema-ddsa is increased up to 5wt%. due to the excellent integrated performance of the polymeric films, hema-ddsa proved to be an effective reactive diluent, which is of potential interest for applications in high performance materials. (c) 2016 society of chemical industry |
| WOS关键词 | EPOXY ACRYLATE RESIN ; PROTECTIVE-COATINGS ; THERMAL-STABILITY ; ACTIVE DILUENT ; PERFORMANCE ; MONOMERS ; PHOTOPOLYMERIZATION ; AGENTS |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000382560500004 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375483 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Kun |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Key Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Lu,Wang, Ying,Zhao, Qiang,et al. Influence of a long-side-chain-containing reactive diluent on the structure and mechanical properties of uv-cured films[J]. Polymer international,2016,65(10):1150-1156. |
| APA | Shen, Lu.,Wang, Ying.,Zhao, Qiang.,Luo, Fubin.,Chen, Junhua.,...&Shi, Jun.(2016).Influence of a long-side-chain-containing reactive diluent on the structure and mechanical properties of uv-cured films.Polymer international,65(10),1150-1156. |
| MLA | Shen, Lu,et al."Influence of a long-side-chain-containing reactive diluent on the structure and mechanical properties of uv-cured films".Polymer international 65.10(2016):1150-1156. |
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来源：中国科学院大学
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