Improved interfacial affinity and co2 separation performance of asymmetric mixed matrix membranes by incorporating postmodified mil-53(ai)
文献类型：期刊论文
| 作者 | Zhu, Haitao1,2; Wang, Lina1; Jie, Xingming1; Liu, Dandan1; Cao, Yiming1 |
| 刊名 | Acs applied materials & interfaces
 |
| 出版日期 | 2016-08-31 |
| 卷号 | 8期号:34页码:22696-22704 |
| ISSN号 | 1944-8244 |
| 关键词 | Postmodified mil-53(al) Preferential adsorption Interfacial affinity Asymmetric mixed matrix membranes Gas separation |
| DOI | 10.1021/acsami.6b07686 |
| 通讯作者 | Cao, yiming(ymcao@dicp.ac.cn) |
| 英文摘要 | Asymmetric mixed matrix membranes(mmms) with mofs hold great application potential for energy-efficient gas separations. however, the particle aggregation and nonselective interfacial microvoids restrict the gas separation performance of asymmetric mmms. herein, nanoporous metal organic framework (mop) of mil-53(al) was modified with aminosilane after solvothermal synthesis. the postfunctionalization by grafting alkyl chains can form hydrogen bonds with polymer chains to enhance the affinity with polymer matrix and facilitate the preferential adsorption of co2 by dipole-quadrupole interaction with the functional group. then the postmodified mil-53(al) was incorporated as filler into poly(ether imide) ultem1000 to fabricate high-quality asymmetric mmms with well dispersed particles in polymer matrix and good adhesion at the mofs-polymer interface. the ultem/s-mil-53(al) asymmetric mmms exhibited remarkable combinations of gas permeance and ideal selectivity for co2/n-2 separation at 10 wt % filler loading. the co2 permeance achieved 24.1 gpu, an increase of 165% compared with pure ultem membrane. meanwhile, the ideal co2/n-2 selectivity also increased from 31.0 up to 41.1. the strategy of post covalent modification for mofs provides an effective way to improve the interfacial affinity and gas separation performance. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; POST-SYNTHETIC MODIFICATION ; GAS SEPARATION ; CO2/CH4 SEPARATION ; TEREPHTHALATE MIL-53 ; INORGANIC FILLERS ; MOLECULAR-SIEVE ; FUNCTIONALIZATION ; ADSORPTION ; SELECTIVITY |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000382514100102 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375486 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, Yiming |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Nation Lib Clean Energy DNL, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Haitao,Wang, Lina,Jie, Xingming,et al. Improved interfacial affinity and co2 separation performance of asymmetric mixed matrix membranes by incorporating postmodified mil-53(ai)[J]. Acs applied materials & interfaces,2016,8(34):22696-22704. |
| APA | Zhu, Haitao,Wang, Lina,Jie, Xingming,Liu, Dandan,&Cao, Yiming.(2016).Improved interfacial affinity and co2 separation performance of asymmetric mixed matrix membranes by incorporating postmodified mil-53(ai).Acs applied materials & interfaces,8(34),22696-22704. |
| MLA | Zhu, Haitao,et al."Improved interfacial affinity and co2 separation performance of asymmetric mixed matrix membranes by incorporating postmodified mil-53(ai)".Acs applied materials & interfaces 8.34(2016):22696-22704. |
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来源：中国科学院大学
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