Tuning the interfacial mechanical behaviors of monolayer graphene/pmma nanocomposites
文献类型：期刊论文
| 作者 | Wang, Guorui1,2; Dai, Zhaohe2,3; Liu, Luqi2; Hu, Hai2; Dai, Qing2; Zhang, Zhong2 |
| 刊名 | Acs applied materials & interfaces
 |
| 出版日期 | 2016-08-31 |
| 卷号 | 8期号:34页码:22554-22562 |
| 关键词 | Graphene Functionalization Raman spectroscopy Interface Failure modes |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.6b03069 |
| 通讯作者 | Liu, luqi(liulq@nanoctr.cn) ; Zhang, zhong(zhong.zhang@nanoctr.cn) |
| 英文摘要 | The van der waals (vdw) force dominated interface between graphene and polymer matrix creates weak points in the mechanical sense. chemical functionalization was expected to be an effective approach in transfer of the outstanding performance of graphene across multiple length scales up to the macroscopic level, due to possible improvements in the interfacial adhesion. however, published works showed the contradiction that improvements, insensitivity, or even worsening of macro-mechanical performance have all been reported in graphene-based polymer nanocomposites. particularly central cause of such discrepancy is the variations in graphene/polymer interfacial chemistry, which is critical in nanocomposites with vast interfacial area. herein, o-3/h2o gaseous mixture was utilized to oxidize monolayer graphene sheet with controlled functionalization degrees. hydrogen bonds (h bonds) are expected to form between oxidized graphene sheet/poly(methyl methacrylate) (pmma) at the interface. on the basis of in situ tensile-micro raman spectroscopy, the impacts of bonding types (vdw and h-bonds) on both key interfacial parameters (such as interfacial shear strength and critical length) and failure modes of graphene/pmma nanocomposite were clarified for the first time at the microscopic level. our results show that owing to improved interfacial interaction via h bonds, the interface tends to be stiffening and strengthening. moreover, the mechanical properties of the functionalized graphene/pmma interface will be set by the competition between the enhanced interfacial adhesion and the degraded elastic modulus of graphene, which was caused by structural defects in the graphene sheet during the functionalization process and could lead to catastrophic failure of graphene sheets in our experimental observation. our results will be helpful to design various nanofiller-based nanocomposites with high mechanical performance. |
| WOS关键词 | POLYMER-BASED NANOCOMPOSITES ; CARBON NANOTUBES ; RAMAN-SPECTROSCOPY ; FUNCTIONALIZED GRAPHENE ; ELASTIC PROPERTIES ; AXIAL-COMPRESSION ; STRESS TRANSFER ; COMPOSITES ; STRENGTH ; SHEETS |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000382514100086 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375609 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Luqi; Zhang, Zhong |
| 作者单位 | 1.Univ Sci & Technol China, Dept Modern Mech, CAS Key Lab Mech Behav & Design Mat, Hefei 230027, Peoples R China 2.CAS Ctr Excellence Nanosci, Natl Ctr Nanosci & Technol, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Guorui,Dai, Zhaohe,Liu, Luqi,et al. Tuning the interfacial mechanical behaviors of monolayer graphene/pmma nanocomposites[J]. Acs applied materials & interfaces,2016,8(34):22554-22562. |
| APA | Wang, Guorui,Dai, Zhaohe,Liu, Luqi,Hu, Hai,Dai, Qing,&Zhang, Zhong.(2016).Tuning the interfacial mechanical behaviors of monolayer graphene/pmma nanocomposites.Acs applied materials & interfaces,8(34),22554-22562. |
| MLA | Wang, Guorui,et al."Tuning the interfacial mechanical behaviors of monolayer graphene/pmma nanocomposites".Acs applied materials & interfaces 8.34(2016):22554-22562. |
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来源：中国科学院大学
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