Promotion effect of cerium and lanthanum oxides on Ni/SBA-15 catalyst for ammonia decomposition
文献类型：期刊论文
| 作者 | Liu, Hongchao1,2; Wang, Hua1; Shen, Jianghan1,2; Sun, Ying1,2; Liu, Zhongmin1 |
| 刊名 | catalysis today
 |
| 出版日期 | 2008-02-29 |
| 卷号 | 131期号:1-4页码:444-449 |
| 关键词 | ammonia decomposition Ni/SBA-15 catalysts cerium lanthanum |
| 产权排序 | 1;1 |
| 通讯作者 | 刘中民 |
| 英文摘要 | ceni/sba-15 and lani/sba-15 catalysts were prepared by deposition-precipitation (dp) method and characterized by n-2 physical adsorption, xrd, h-2-tpr, h-2-chemisorption and tem. their catalytic performances in the ammonia decomposition reaction were tested and compared with ni/sba-15 catalyst. addition of cerium and lanthanum oxides to the ni/sba-15 catalyst caused some decrease of bet surface area and pore volume of the catalysts, but led to a promotion effect to their catalytic activity which was closely related to the ratio of cc (la)/ni. the highest conversion of ammonia could be obtained when the ce (la)/ni ratio was around 0.3. the promotion effect is more evident on ceni/ sba-15(0.3) than on lani/sba-15(0.3) catalyst under identical reaction conditions. the ceni/sba-15 and lani/sba-15 catalysts show smaller nickel particle size and easier reducibility in comparison with the ni/sba-15 catalysts. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | cox-free hydrogen ; supported nickel-catalysts ; fuel-cell applications ; ruthenium catalysts ; nh3 decomposition ; deposition-precipitation ; generation ; surface ; alumina ; silica |
| 收录类别 | ISTP ; SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000253382100062 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/100623]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Appl Catalysis Lab, Dalian 116023, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hongchao,Wang, Hua,Shen, Jianghan,et al. Promotion effect of cerium and lanthanum oxides on Ni/SBA-15 catalyst for ammonia decomposition[J]. catalysis today,2008,131(1-4):444-449. |
| APA | Liu, Hongchao,Wang, Hua,Shen, Jianghan,Sun, Ying,&Liu, Zhongmin.(2008).Promotion effect of cerium and lanthanum oxides on Ni/SBA-15 catalyst for ammonia decomposition.catalysis today,131(1-4),444-449. |
| MLA | Liu, Hongchao,et al."Promotion effect of cerium and lanthanum oxides on Ni/SBA-15 catalyst for ammonia decomposition".catalysis today 131.1-4(2008):444-449. |
入库方式： OAI收割
来源：大连化学物理研究所
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