Reversible phase transition driven by order-disorder transformations of metal-halide moieties in [(c6h14)nh2](2)center dot cubr4
文献类型：期刊论文
| 作者 | Asghar, Muhammad Adnan1,2; Zhang, Shuquan1; Khan, Tariq1,2; Sun, Zhihua1; Zeb, Aurang1,2; Ji, Chengmin1; Li, Lina1; Zhao, Sangen1; Luo, Junhua1 |
| 刊名 | Journal of materials chemistry c
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:32页码:7537-7540 |
| ISSN号 | 2050-7526 |
| DOI | 10.1039/c6tc02034h |
| 通讯作者 | Zhang, shuquan(sqzhang@fzu.edu.cn) |
| 英文摘要 | A novel phase transition has been discovered where the phase transition is primarily accomplished by the order-disorder transformation of metal-coordinated halogen atoms in an organic-inorganic hybrid material [(c6h14)nh2](2)center dot cubr4 (1). its phase transition behaviour was verified by specific heat capacity (c-p) and differential scanning calorimetry (dsc) measurements with a thermal hysteresis at 4.8 k. the dielectric measurements of 1 show a distinct step-like anomaly around t-c, demonstrating two states at two different phases, which enlightens that 1 can be conceived as a potential switchable dielectric material. moreover, temperature-dependent single-crystal x-ray diffraction analyses of 1 disclose that disordering of metal-halides together with reorientations of the cations is the cause of this unique phase-transition material. all these results open a new way to design and assemble novel phase transition materials. |
| WOS关键词 | NONLINEAR-OPTICAL PROPERTIES ; COMPOUND ; TRIFLUOROMETHANESULFONATE ; BEHAVIOR ; CRYSTAL ; SWITCH ; STATES |
| WOS研究方向 | Materials Science ; Physics |
| WOS类目 | Materials Science, Multidisciplinary ; Physics, Applied |
| 语种 | 英语 |
| WOS记录号 | WOS:000381435900002 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375622 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Shuquan |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Asghar, Muhammad Adnan,Zhang, Shuquan,Khan, Tariq,et al. Reversible phase transition driven by order-disorder transformations of metal-halide moieties in [(c6h14)nh2](2)center dot cubr4[J]. Journal of materials chemistry c,2016,4(32):7537-7540. |
| APA | Asghar, Muhammad Adnan.,Zhang, Shuquan.,Khan, Tariq.,Sun, Zhihua.,Zeb, Aurang.,...&Luo, Junhua.(2016).Reversible phase transition driven by order-disorder transformations of metal-halide moieties in [(c6h14)nh2](2)center dot cubr4.Journal of materials chemistry c,4(32),7537-7540. |
| MLA | Asghar, Muhammad Adnan,et al."Reversible phase transition driven by order-disorder transformations of metal-halide moieties in [(c6h14)nh2](2)center dot cubr4".Journal of materials chemistry c 4.32(2016):7537-7540. |
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来源：中国科学院大学
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