A nonanuclear nickel cluster-based coordination polymer for solar hydrogen production from water in open atmosphere
文献类型：期刊论文
| 作者 | Feng, Ya-Nan1,2; Du, Shao-Wu1 |
| 刊名 | Applied catalysis b-environmental
 |
| 出版日期 | 2016-12-05 |
| 卷号 | 198页码:404-410 |
| 关键词 | Cluster-based cp Solar-driven h-2 production Aerotolerance |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2016.05.072 |
| 通讯作者 | Du, shao-wu(swdu@fjirsm.ac.cn) |
| 英文摘要 | In this work, a novel 2d double-layered metal-organic coordination polymer, [ni-9(hmna)(2)(mna)(8)(h2o)(10)]center dot(h2o)(11) (1) (h(2)mna=2-mercaptonicotinic acid), based on a nonanuclear nickel cluster was synthesized to function as an efficient heterogeneous catalyst with an optimized ton of 685.4 for solar-driven h-2 production from water. both the solar conversion and water utilization were achieved simultaneously in this photocatalytic system. without the protection of inert atmosphere, the catalyst was still able to produce hydrogen with a ton of 93.5 in air. the influence of oxygen was studied by virtue of cyclic voltammograms (cvs) and uv-vis adsorption spectrum. the active radicals generated in the photocatalytical process were examined by in-situ electron paramagnetic resonance (epr) experiments which provided solid evidence to support the reductive mechanism. (c) 2016 elsevier b.v. all rights reserved. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; PHOTOCATALYTIC CO2 REDUCTION ; VISIBLE-LIGHT ; GENERATION ; CATALYST ; SEPARATION ; COMPLEXES ; EVOLUTION ; SYSTEM ; SITES |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000381950000041 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375640 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Du, Shao-Wu |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Ya-Nan,Du, Shao-Wu. A nonanuclear nickel cluster-based coordination polymer for solar hydrogen production from water in open atmosphere[J]. Applied catalysis b-environmental,2016,198:404-410. |
| APA | Feng, Ya-Nan,&Du, Shao-Wu.(2016).A nonanuclear nickel cluster-based coordination polymer for solar hydrogen production from water in open atmosphere.Applied catalysis b-environmental,198,404-410. |
| MLA | Feng, Ya-Nan,et al."A nonanuclear nickel cluster-based coordination polymer for solar hydrogen production from water in open atmosphere".Applied catalysis b-environmental 198(2016):404-410. |
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来源：中国科学院大学
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