One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran
文献类型：期刊论文
| 作者 | Xiang, Xiaomin1,2; Cui, Jinglei1,2; Ding, Guoqiang3; Zheng, Hongyan3; Zhu, Yulei1,3; Li, Yongwang1,3 |
| 刊名 | Acs sustainable chemistry & engineering
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 4期号:9页码:4506-4510 |
| 关键词 | Hy zeolite Gamma-butyrolactone Ht-cu/zno/al2o3 5-hydroxymethylfurfural Biomass |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.6b01411 |
| 通讯作者 | Zhu, yulei(zhuyulei@sxicc.ac.cn) |
| 英文摘要 | Selective conversion of fructose to fuels and fine chemicals is an important step for biomass utilization. in this paper, direct conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran was first realized over combined hy zeolite and inexpensive hydrotalcite (ht)-cu/zno/al2o3 in a fixed-bed reactor. the cooperative effect of hy zeolite and gamma-butyrolactone solvent facilitated the dehydration of fructose into 5-hydroxymethylfurfural. by adjusting the hydrogenation temperature for hmf over ht-cu/zno/al2o3 catalyst, high yields of 2,5-dihydroxymethylfuran (48.2%) at 140 degrees c and 2,5-dimethylfuran (40.6%) at 240 degrees c were obtained, respectively. |
| WOS关键词 | SELECTIVE HYDROGENATION ; ZEOLITE CATALYST ; CU-CATALYSTS ; BIOMASS ; FUELS ; METAL ; HMF |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Multidisciplinary ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000382713100005 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375670 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhu, Yulei |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, 27 South Taoyuan Rd, Taiyuan 030001, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Synfuels China Co Ltd, Taiyuan 030032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Xiaomin,Cui, Jinglei,Ding, Guoqiang,et al. One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran[J]. Acs sustainable chemistry & engineering,2016,4(9):4506-4510. |
| APA | Xiang, Xiaomin,Cui, Jinglei,Ding, Guoqiang,Zheng, Hongyan,Zhu, Yulei,&Li, Yongwang.(2016).One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran.Acs sustainable chemistry & engineering,4(9),4506-4510. |
| MLA | Xiang, Xiaomin,et al."One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran".Acs sustainable chemistry & engineering 4.9(2016):4506-4510. |
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来源：中国科学院大学
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