Novel pd13cu3s7 nanotubes with high electrocatalytic activity towards both oxygen reduction and ethanol oxidation reactions
文献类型：期刊论文
| 作者 | Du, Cheng1,2; He, Shuijian1,2; Liu, Minmin1,2; Gao, Xiaohui1,2; Zhang, Ruizhong1,2; Chen, Wei1 |
| 刊名 | Crystengcomm
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:32页码:6055-6061 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/c6ce00688d |
| 通讯作者 | Chen, wei(weichen@ciac.ac.cn) |
| 英文摘要 | In the search for more effective and stable fuel cell electrocatalysts, we have developed a facile method to synthesize novel pd13cu3s7 nanotubes (pd13cu3s7 nts) for the first time. x-ray diffraction (xrd), x-ray photoelectron spectroscopy (xps), scanning electron microscopy (sem) and high-resolution transmission electron microscopy (hrtem) measurements have been used to characterize the structure, components and morphology of the pd13cu3s7 nts. due to their novel structure and composition, the as-prepared pd13cu3s7 nts showed a high oxygen reduction reaction (orr) catalytic performance, with similar catalytic activity to that of commercial pt/c but with better stability than pt/c. furthermore, the orr catalyzed by the pd13cu3s7 nts was calculated to be a directly 4e(-) process. on the other hand, the pd13cu3s7 nts also exhibited excellent ethanol oxidation reaction (eor) activity (2.7 ma cm(-2)), which is about five times that of commercial pd/c (0.55 ma cm(-2)). an eis study indicated that the charge transfer resistance of the pd13cu3s7 nts is much lower than that of commercial pd/c in the eor. |
| WOS关键词 | FUEL-CELLS ; GALVANIC REPLACEMENT ; ALLOY NANOPARTICLES ; COPPER NANOWIRES ; FORMIC-ACID ; CATALYSTS ; PD ; ELECTROOXIDATION ; EFFICIENT ; PERFORMANCE |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Multidisciplinary ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000381432500012 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375691 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, Wei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Cheng,He, Shuijian,Liu, Minmin,et al. Novel pd13cu3s7 nanotubes with high electrocatalytic activity towards both oxygen reduction and ethanol oxidation reactions[J]. Crystengcomm,2016,18(32):6055-6061. |
| APA | Du, Cheng,He, Shuijian,Liu, Minmin,Gao, Xiaohui,Zhang, Ruizhong,&Chen, Wei.(2016).Novel pd13cu3s7 nanotubes with high electrocatalytic activity towards both oxygen reduction and ethanol oxidation reactions.Crystengcomm,18(32),6055-6061. |
| MLA | Du, Cheng,et al."Novel pd13cu3s7 nanotubes with high electrocatalytic activity towards both oxygen reduction and ethanol oxidation reactions".Crystengcomm 18.32(2016):6055-6061. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。