The effect of mg(oh)(2) on furfural oxidation with h2o2
文献类型：期刊论文
| 作者 | Xiang, Xiaomin1,2; Zhang, Bin1; Ding, Guoqiang3; Cui, Jinglei1,2; Zheng, Hongyan3; Zhu, Yulei1,3 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2016-11-05 |
| 卷号 | 86页码:41-45 |
| 关键词 | Furfural 2(5h)-furanone Succinic acid Mg(oh)(2) Biomass |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2016.08.013 |
| 通讯作者 | Zhu, yulei(zhuyulei@sxicc.ac.cn) |
| 英文摘要 | The oxidation of furfural in h2o2 and h2o2-mg(oh)(2) system were systematically investigated and a rational explanation for the reaction mechanism was proposed. 2-formyloxyfuran, from selective oxidation of -hc=0 group in furfural, was a crucial intermediate. the addition of mg(oh)(2) suppressed the oxidation of furan ring of furfural and enhanced selectivities of 2(5h)-furanone (44.8%) and succinic acid (38.0%). ft-ir, gaussian calculation and experimental results indicated that the process of furfural oxidation with h2o2 is homogeneous, and the synergy between dissolved mg2+ cations and oh- ions facilitates the hoo- attacking the carbon atom of -hc=0 other than the c=c bound of furan ring. (c) 2016 elsevier b.v. all rights reserved. |
| WOS关键词 | SUCCINIC ACID ; CONVERSION ; CATALYSTS ; BIOMASS ; MEDIA ; HYDROGENATION ; PLATFORM ; SITES ; METAL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000384385900010 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375774 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhu, Yulei |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Synfuels China Co Ltd, Taiyuan 030032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Xiaomin,Zhang, Bin,Ding, Guoqiang,et al. The effect of mg(oh)(2) on furfural oxidation with h2o2[J]. Catalysis communications,2016,86:41-45. |
| APA | Xiang, Xiaomin,Zhang, Bin,Ding, Guoqiang,Cui, Jinglei,Zheng, Hongyan,&Zhu, Yulei.(2016).The effect of mg(oh)(2) on furfural oxidation with h2o2.Catalysis communications,86,41-45. |
| MLA | Xiang, Xiaomin,et al."The effect of mg(oh)(2) on furfural oxidation with h2o2".Catalysis communications 86(2016):41-45. |
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来源：中国科学院大学
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