Iron and nitrogen co-doped hierarchical porous graphitic carbon for a high-efficiency oxygen reduction reaction in a wide range of ph
文献类型：期刊论文
| 作者 | Gu, Wenling1,3; Hu, Liuyong2,3; Li, Jing1; Wang, Erkang1 |
| 刊名 | Journal of materials chemistry a
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:37页码:14364-14370 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c6ta05516h |
| 通讯作者 | Li, jing(lijingce@ciac.ac.cn) ; Wang, erkang(ekwang@ciac.ac.cn) |
| 英文摘要 | Developing an efficient, easy-to-fabricate and applicable noble-metal-free catalyst for the oxygen reduction reaction (orr) is extremely necessary for fuel cells. in this context, by pyrolyzing a nontoxic and low-cost iron-coordinated polydopamine polymer (fe-pda-30, 30 represents the polymerization time) precursor at 800 degrees c, a template-free oxygen reduction reaction (orr) catalyst iron and nitrogen co-doped hierarchical porous graphitic carbon (fe, n/pgc-30) was obtained. the obtained catalyst fe, n/pgc-30, first reported here, manifests outstanding oxygen reduction activity in a wide range of ph. it is worth nothing that the catalyst exhibits remarkable orr activity with a more positive half-wave potential of 15 mv than that of the commercial pt/c catalyst under alkaline conditions. additionally, the activity of the catalyst is comparable to that of commercial pt/c under neutral and acidic conditions with almost a 4e(-) reaction process and very low h2o2 yield. this catalyst provides an exciting direction for non-precious metal electrocatalysts with excellent oxygen reduction activity in a wide range of ph. these favorable results demonstrate that the catalyst fe, n/pgc-30 can serve as a highly efficient and stable orr catalyst for practical fuel cell applications. |
| WOS关键词 | EVOLUTION REACTIONS ; FE-N/C ; CATALYST ; ELECTROCATALYSTS ; PERFORMANCE ; COMPLEXES ; PORPHYRIN ; COMPOSITE ; ALKALINE ; HYBRIDS |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| WOS类目 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000384444200034 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375873 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Jing; Wang, Erkang |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Wenling,Hu, Liuyong,Li, Jing,et al. Iron and nitrogen co-doped hierarchical porous graphitic carbon for a high-efficiency oxygen reduction reaction in a wide range of ph[J]. Journal of materials chemistry a,2016,4(37):14364-14370. |
| APA | Gu, Wenling,Hu, Liuyong,Li, Jing,&Wang, Erkang.(2016).Iron and nitrogen co-doped hierarchical porous graphitic carbon for a high-efficiency oxygen reduction reaction in a wide range of ph.Journal of materials chemistry a,4(37),14364-14370. |
| MLA | Gu, Wenling,et al."Iron and nitrogen co-doped hierarchical porous graphitic carbon for a high-efficiency oxygen reduction reaction in a wide range of ph".Journal of materials chemistry a 4.37(2016):14364-14370. |
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来源：中国科学院大学
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