Comprehensive appraisal and application of novel extraction system for heavy rare earth separation on the basis of coordination equilibrium effect
文献类型：期刊论文
| 作者 | Chen, Li1,2; Chen, Ji1; Jing, Yu1; Li, Deqian1 |
| 刊名 | Hydrometallurgy
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 165页码:351-357 |
| ISSN号 | 0304-386X |
| 关键词 | Coordination equilibrium effect Thermodynamics study Apparent kinetics study Heavy rare earths Separation |
| DOI | 10.1016/j.hydromet.2015.12.007 |
| 通讯作者 | Chen, ji(jchen@ciac.ac.cn) |
| 英文摘要 | Several novel extraction systems were reported since 2-ethylhexyl phosphonic acid mono-(2-ethylhexyl) ester (p507) had been confronted with low selectivity and incomplete stripping for heavy rare earths (hres). this paper makes a comprehensive appraisal of p507, bis (2,4,4-trimethylpentyl) phosphinic acid (cyanex272), mixture of p507 and cyanex272, p507 adding isooctanol and bifunctional ionic liquid extractant (bif-ile) [trialkylmethyl-ammonium][di-(2-ethylhexyl)orthophosphinate] ([a336][p507]). thermodynamics study, apparent kinetics study and theoretical calculation for the cascade extraction are all included. we put forward coordination equilibrium effect for the first time to illustrate the inner and outer environment during the coordination. it could be useful to explain the extraction ability and selectivity of different extractants. all these would provide separation of hres with more feasible and informative understanding and guidance. (c) 2015 elsevier b.v. all rights reserved. |
| WOS关键词 | ACID MONO-2-ETHYLHEXYL ESTER ; 2-ETHYLHEXYL PHOSPHONIC ACID ; SOLVENT-EXTRACTION ; IONIC LIQUIDS ; BIS(2,4,4-TRIMETHYLPENTYL)PHOSPHINIC ACID ; PHOSPHINIC ACID ; MIXTURES ; STRATEGY ; METALS |
| WOS研究方向 | Metallurgy & Metallurgical Engineering |
| WOS类目 | Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000383522100021 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375966 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, Ji |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resources Utilizat, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Li,Chen, Ji,Jing, Yu,et al. Comprehensive appraisal and application of novel extraction system for heavy rare earth separation on the basis of coordination equilibrium effect[J]. Hydrometallurgy,2016,165:351-357. |
| APA | Chen, Li,Chen, Ji,Jing, Yu,&Li, Deqian.(2016).Comprehensive appraisal and application of novel extraction system for heavy rare earth separation on the basis of coordination equilibrium effect.Hydrometallurgy,165,351-357. |
| MLA | Chen, Li,et al."Comprehensive appraisal and application of novel extraction system for heavy rare earth separation on the basis of coordination equilibrium effect".Hydrometallurgy 165(2016):351-357. |
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来源：中国科学院大学
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