中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes

文献类型:期刊论文

作者Zhong, Haixia1,2; Wang, Jun1; Meng, Fanlu1; Zhang, Xinbo1
刊名Angewandte chemie-international edition
出版日期2016-08-16
卷号55期号:34页码:9937-9941
关键词Corrosion Electrocatalysts Iron Oxygen evolution reaction Rust
ISSN号1433-7851
DOI10.1002/anie.201604040
通讯作者Zhang, xinbo(xbzhang@ciac.ac.cn)
英文摘要Developing effective ways to recycle rusted stainless steel and to promote the sluggish oxygen evolution reaction (oer), associated with water splitting and metal-air batteries, is important for a resource-sustainable and environment-friendly society. herein, we propose a strategy to enable rusted stainless steel plate to be used as an abundant and low-cost oer catalyst, wherein a hydrothermal combined in situ electrochemical oxidation-reduction cycle (eorc) method is developed to mimic and expedite the corrosion process, and thus activate stainless steel into free-standing oer electrodes. benefiting from the plentiful electrolyte-accessible fe/(ni) oxyhydroxides, high conductivity and mechanical stability, this electrode exhibits remarkable oer performances including low overpotential, fast kinetics, and long-term durability. the slight degradation in current after long-term use can be repaired immediately in situ by an eorc.
WOS关键词LAYERED-DOUBLE-HYDROXIDE ; WATER-OXIDATION ; SURFACE OXIDATION ; STAINLESS-STEEL ; ELECTROCATALYSTS ; COBALT ; IRON ; NANOSHEETS ; GRAPHENE ; CATALYST
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000383373000020
出版者WILEY-V C H VERLAG GMBH
URI标识http://www.irgrid.ac.cn/handle/1471x/2376012
专题中国科学院大学
通讯作者Zhang, Xinbo
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhong, Haixia,Wang, Jun,Meng, Fanlu,et al. In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes[J]. Angewandte chemie-international edition,2016,55(34):9937-9941.
APA Zhong, Haixia,Wang, Jun,Meng, Fanlu,&Zhang, Xinbo.(2016).In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes.Angewandte chemie-international edition,55(34),9937-9941.
MLA Zhong, Haixia,et al."In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes".Angewandte chemie-international edition 55.34(2016):9937-9941.

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来源:中国科学院大学

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