In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes
文献类型:期刊论文
作者 | Zhong, Haixia1,2; Wang, Jun1; Meng, Fanlu1; Zhang, Xinbo1 |
刊名 | Angewandte chemie-international edition
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出版日期 | 2016-08-16 |
卷号 | 55期号:34页码:9937-9941 |
关键词 | Corrosion Electrocatalysts Iron Oxygen evolution reaction Rust |
ISSN号 | 1433-7851 |
DOI | 10.1002/anie.201604040 |
通讯作者 | Zhang, xinbo(xbzhang@ciac.ac.cn) |
英文摘要 | Developing effective ways to recycle rusted stainless steel and to promote the sluggish oxygen evolution reaction (oer), associated with water splitting and metal-air batteries, is important for a resource-sustainable and environment-friendly society. herein, we propose a strategy to enable rusted stainless steel plate to be used as an abundant and low-cost oer catalyst, wherein a hydrothermal combined in situ electrochemical oxidation-reduction cycle (eorc) method is developed to mimic and expedite the corrosion process, and thus activate stainless steel into free-standing oer electrodes. benefiting from the plentiful electrolyte-accessible fe/(ni) oxyhydroxides, high conductivity and mechanical stability, this electrode exhibits remarkable oer performances including low overpotential, fast kinetics, and long-term durability. the slight degradation in current after long-term use can be repaired immediately in situ by an eorc. |
WOS关键词 | LAYERED-DOUBLE-HYDROXIDE ; WATER-OXIDATION ; SURFACE OXIDATION ; STAINLESS-STEEL ; ELECTROCATALYSTS ; COBALT ; IRON ; NANOSHEETS ; GRAPHENE ; CATALYST |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000383373000020 |
出版者 | WILEY-V C H VERLAG GMBH |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376012 |
专题 | 中国科学院大学 |
通讯作者 | Zhang, Xinbo |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhong, Haixia,Wang, Jun,Meng, Fanlu,et al. In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes[J]. Angewandte chemie-international edition,2016,55(34):9937-9941. |
APA | Zhong, Haixia,Wang, Jun,Meng, Fanlu,&Zhang, Xinbo.(2016).In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes.Angewandte chemie-international edition,55(34),9937-9941. |
MLA | Zhong, Haixia,et al."In situ activating ubiquitous rust towards low-cost, efficient, free-standing, and recoverable oxygen evolution electrodes".Angewandte chemie-international edition 55.34(2016):9937-9941. |
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来源:中国科学院大学
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