Asymmetric catalysis with metal complexes in nanoreactors
文献类型：期刊论文
| 作者 | Yang, Qihua; Han, Difei; Yang, Hengquan; Li, Can |
| 刊名 | chemistry-an asian journal
 |
| 出版日期 | 2008 |
| 卷号 | 3期号:8-9页码:1214-1229 |
| 关键词 | asymmetric catalysis epoxidation heterogeneous catalysis nanoreactors organosilicas |
| 产权排序 | 1;1 |
| 通讯作者 | 李灿 |
| 英文摘要 | recently, the field of heterogeneous asymmetric catalysis, generally using chiral solid catalysts, has attracted much attention in the production of single enantiomers. among versatile chiral solid catalysts, chiral metal complexes confined in nanoreactors often exhibit very unique enantioselectivity and catalytic activity compared to homogeneous catalysts. in this focus review, we summarize the recent advances in asymmetric reactions on chiral metal complexes confined in nanoreactors with an emphasis on the confinement effect and cooperative activation effect of the nanoreactor and new strategies for the preparation of chiral solid catalysts, such as the encapsulation of chiral metal complexes in the nanocages of mesoporous silica and incorporation of chiral ligands in the network of mesoporous organosilicas. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | periodic mesoporous organosilicas ; heterogeneous enantioselective reactions ; supported chiral catalysts ; mn(iii) salen complexes ; diels-alder reaction ; a-bottle synthesis ; unfunctionalized olefins ; nonfunctionalized alkenes ; organic groups ; zeolite-y |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000259119400001 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/100713]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Qihua,Han, Difei,Yang, Hengquan,et al. Asymmetric catalysis with metal complexes in nanoreactors[J]. chemistry-an asian journal,2008,3(8-9):1214-1229. |
| APA | Yang, Qihua,Han, Difei,Yang, Hengquan,&Li, Can.(2008).Asymmetric catalysis with metal complexes in nanoreactors.chemistry-an asian journal,3(8-9),1214-1229. |
| MLA | Yang, Qihua,et al."Asymmetric catalysis with metal complexes in nanoreactors".chemistry-an asian journal 3.8-9(2008):1214-1229. |
入库方式： OAI收割
来源：大连化学物理研究所
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