Catalytic oxidative c-c bond cleavage route of levulinic acid and methyl levulinate
文献类型：期刊论文
| 作者 | Xia, Fei1,2; Du, Zhongtian3; Liu, Junxia1; Ma, Yangyang1,2; Xu, Jie1 |
| 刊名 | Rsc advances
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:76页码:72744-72749 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra16149a |
| 通讯作者 | Xu, jie(xujie@dicp.ac.cn) |
| 英文摘要 | Recently, obtaining value-added chemicals from biomass resources has attracted considerable attention. levulinic acid is one of the most important biomass platform compounds, which could be obtained from carbohydrate biomass. in this work, levulinic acid was selectively converted into c4 product, including succinic anhydride, via catalytic oxidation with a manganese catalyst in acetic anhydride. moreover, an unexpected product of maleic anhydride was obtained, which greatly differs from that of levulinate ester. the pathway for formation of maleic anhydride was studied by monitoring and confirming intermediates alpha-angelica lactone and its derivative 2-methyl-5-oxotetrahydro-2-furanyl acetate. based on the obtained mechanistic information, the different behaviour between the oxidative cleavage of levulinic acid and levulinate ester was further discussed. |
| WOS关键词 | MALEIC-ANHYDRIDE ; SUCCINIC ANHYDRIDE ; SELECTIVE HYDROGENATION ; PHASE HYDROGENATION ; RENEWABLE RESOURCES ; NICKEL-CATALYSTS ; LIQUID-PHASE ; N-BUTANE ; BIOMASS ; CONVERSION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000381513300110 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376176 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Jie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Dalian Univ Technol, Sch Petr & Chem Engn, Panjin 124221, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Fei,Du, Zhongtian,Liu, Junxia,et al. Catalytic oxidative c-c bond cleavage route of levulinic acid and methyl levulinate[J]. Rsc advances,2016,6(76):72744-72749. |
| APA | Xia, Fei,Du, Zhongtian,Liu, Junxia,Ma, Yangyang,&Xu, Jie.(2016).Catalytic oxidative c-c bond cleavage route of levulinic acid and methyl levulinate.Rsc advances,6(76),72744-72749. |
| MLA | Xia, Fei,et al."Catalytic oxidative c-c bond cleavage route of levulinic acid and methyl levulinate".Rsc advances 6.76(2016):72744-72749. |
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来源：中国科学院大学
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