A multifunctional mn-ii phosphonate for rapid separation of methyl orange and electron-transfer photochromism
文献类型：期刊论文
| 作者 | Gao, Chao-Ying1,3; Yang, Yang2; Ai, Jing1,3; Tian, Hong-Rui1; Li, Lei-Jiao1; Yang, Weiting1; Dang, Song1; Sun, Zhong-Ming1 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2016-08-08 |
| 卷号 | 22期号:33页码:11652-11659 |
| 关键词 | Metal-organic frameworks Methyl orange Mn-ii phosphonate Photochromism Rapid separation |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201601318 |
| 通讯作者 | Sun, zhong-ming(szm@ciac.ac.cn) |
| 英文摘要 | A mn-ii phosphonate of the general formula [mn(h2l)(2)(h2o)(2)(h(2)bibp)] adopts a layered motif with protonated h(2)bibp(2+) cations embedded in the channels (h4l= thiophene-2-phosphonic acid; bibp=4,4'-bis(1-imidazolyl)biphenyl). the title compound exhibits excellent adsorptive removal of methyl orange (mo) dye from aqueous solution. its advantageous features include fast adsorption, high uptake capacity, selective removal, and reusability, which are of great significance for practical application in wastewater treatment. meanwhile, the compound displays rapid photochromism upon irradiation with visible light at room temperature. extensive research has demonstrated that such behavior is based on a ligand-to-ligand charge-transfer (llct) mechanism. the irradiated sample possesses an ultra-long-lived charge-separated state. moreover, not only is the compound the first mn-based photochromic mof, but it is also one of the very few examples showing llct with non-photochromic components. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; EFFECTIVE CORE POTENTIALS ; CHROMATOGRAPHIC DYE SEPARATION ; MULTIWALLED CARBON NANOTUBES ; LIVED CHARGE SEPARATION ; AQUEOUS-SOLUTION ; MOLECULAR CALCULATIONS ; COORDINATION POLYMER ; FLUORESCENT PROPERTIES ; ENERGY-TRANSFER |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000382921600026 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376246 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Sun, Zhong-Ming |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China 2.Inner Mongolia Univ Nationalities, Coll Chem & Chem Engn, Tongliao 028000, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Chao-Ying,Yang, Yang,Ai, Jing,et al. A multifunctional mn-ii phosphonate for rapid separation of methyl orange and electron-transfer photochromism[J]. Chemistry-a european journal,2016,22(33):11652-11659. |
| APA | Gao, Chao-Ying.,Yang, Yang.,Ai, Jing.,Tian, Hong-Rui.,Li, Lei-Jiao.,...&Sun, Zhong-Ming.(2016).A multifunctional mn-ii phosphonate for rapid separation of methyl orange and electron-transfer photochromism.Chemistry-a european journal,22(33),11652-11659. |
| MLA | Gao, Chao-Ying,et al."A multifunctional mn-ii phosphonate for rapid separation of methyl orange and electron-transfer photochromism".Chemistry-a european journal 22.33(2016):11652-11659. |
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来源：中国科学院大学
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