Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability
文献类型：期刊论文
| 作者 | Li, Hui1,2; Ding, Xuesong1; Han, Bao-Hang1 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2016-08-08 |
| 卷号 | 22期号:33页码:11863-11868 |
| 关键词 | Gas adsorption Iodine Phthalocyanine Porous polymers Porphyrins |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201602337 |
| 通讯作者 | Ding, xuesong(dingxs@nanoctr.cn) ; Han, bao-hang(hanbh@nanoctr.cn) |
| 英文摘要 | We report a highly efficient iodine adsorbent achieved by rational design of a porous azo-bridged porphyrinphthalocyanine network (azoppn), which was synthesized by a catalyst-free coupling reaction between free-base 5,10,15,20-tetrakis(4-nitrophenyl)-porphyrin and nickel tetraaminophthlocyanine. azoppn has a permanent porous structure and plenty of porphyrin and phthalocyanine units in the skeleton as effective sorption sites. it displays excellent adsorption of iodine vapor up to 290 wt.% and also shows remarkable capability as adsorbent for iodine in solution. this strategy of combining physisorption with chemisorption in one adsorbent will pave the way for the development of new materials for iodine capture. |
| WOS关键词 | CONJUGATED MICROPOROUS POLYMER ; COVALENT ORGANIC FRAMEWORK ; ELECTRICAL-CONDUCTIVITY ; HETEROGENEOUS CATALYSIS ; RADIOACTIVE IODINE ; VOLATILE IODINE ; GAS-STORAGE ; CO2 CAPTURE ; WASTE FORMS ; TEMPERATURE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000382921600049 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376294 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Ding, Xuesong; Han, Bao-Hang |
| 作者单位 | 1.Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hui,Ding, Xuesong,Han, Bao-Hang. Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability[J]. Chemistry-a european journal,2016,22(33):11863-11868. |
| APA | Li, Hui,Ding, Xuesong,&Han, Bao-Hang.(2016).Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability.Chemistry-a european journal,22(33),11863-11868. |
| MLA | Li, Hui,et al."Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability".Chemistry-a european journal 22.33(2016):11863-11868. |
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来源：中国科学院大学
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