Negative cooperativity in the binding of lmidazolium and viologen ions to a pillar[5]arene-crown ether fused host
文献类型:期刊论文
作者 | Hu, Wei-Bo1,2; Hu, Wen-Jing1; Liu, Yahu A.3; Li, Jiu-Sheng1; Jiang, Biao1; Wen, Ke1,4 |
刊名 | Organic letters
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出版日期 | 2015-06-19 |
卷号 | 17期号:12页码:2940-2943 |
ISSN号 | 1523-7060 |
DOI | 10.1021/acs.orglett.5b01209 |
通讯作者 | Li, jiu-sheng(lijs@sari.ac.cn) |
英文摘要 | A pillar[5]arene-crown ether fused bicyclic host 1 was found to be able to recognize an imidazolium ion g1 by its pillar[5]arene subunit and a viologen ion g2 by its crown ether receptor discriminatively. the simultaneous binding of g1 and g2 by 1 resulted in the formation of a three-component host-guest complex g1 subset of 1 superset of g2. negative heterotropic cooperative effects were displayed by g1 and g2 in their binding to 1 and were investigated by stepwise bindings of g1 and g2 to 1. |
WOS关键词 | MOLECULAR RECOGNITION ; GUEST COMPLEXATION ; HEMOGLOBIN ; PORPHYRIN ; PARAQUAT ; ASSEMBLIES ; COMPLEXITY ; RECEPTORS ; KINETICS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
WOS记录号 | WOS:000356845000020 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376389 |
专题 | 中国科学院大学 |
通讯作者 | Li, Jiu-Sheng |
作者单位 | 1.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.ChemBridge Res Labs Inc, Med Chem, San Diego, CA 92127 USA 4.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, Wei-Bo,Hu, Wen-Jing,Liu, Yahu A.,et al. Negative cooperativity in the binding of lmidazolium and viologen ions to a pillar[5]arene-crown ether fused host[J]. Organic letters,2015,17(12):2940-2943. |
APA | Hu, Wei-Bo,Hu, Wen-Jing,Liu, Yahu A.,Li, Jiu-Sheng,Jiang, Biao,&Wen, Ke.(2015).Negative cooperativity in the binding of lmidazolium and viologen ions to a pillar[5]arene-crown ether fused host.Organic letters,17(12),2940-2943. |
MLA | Hu, Wei-Bo,et al."Negative cooperativity in the binding of lmidazolium and viologen ions to a pillar[5]arene-crown ether fused host".Organic letters 17.12(2015):2940-2943. |
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来源:中国科学院大学
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