Direct enantioselective amination of alpha-ketoester catalyzed by tertiary amine thiourea: a new approach to chiral alpha-hydroxy-beta-amino acid
文献类型：期刊论文
| 作者 | Fu, Ji-Ya2,3; Wang, Qi-Lin1,3; Gui, Yong-Yuan1,3; Wang, Li-Xin1 |
| 刊名 | Tetrahedron letters
 |
| 出版日期 | 2015-07-08 |
| 卷号 | 56期号:28页码:4220-4223 |
| 关键词 | Enantioselective amination Ketoesters Chiral tertiary amine thioureas Alpha-flydroxy-beta-amino acids |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2015.05.061 |
| 通讯作者 | Wang, li-xin(wlxioc@cioc.ac.cn) |
| 英文摘要 | A highly enantioselective amination of alpha-ketoesters catalyzed by chiral tertiary amine thioureas was reported to afford alpha-hydroxy-beta-amino acids with two continuous stereocenters in high yields (up to 90%) and enantioselectivities (up to 93% ee). (c) 2015 elsevier ltd. all rights reserved. |
| WOS关键词 | ASYMMETRIC CATALYSIS ; BOND DONORS ; DEGRADATION ; ANALOGS ; BINDING ; CIAP1 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000356757200017 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376461 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Li-Xin |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Henan Univ, Coll Chem & Chem Engn, Kaifeng 475004, Henan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Ji-Ya,Wang, Qi-Lin,Gui, Yong-Yuan,et al. Direct enantioselective amination of alpha-ketoester catalyzed by tertiary amine thiourea: a new approach to chiral alpha-hydroxy-beta-amino acid[J]. Tetrahedron letters,2015,56(28):4220-4223. |
| APA | Fu, Ji-Ya,Wang, Qi-Lin,Gui, Yong-Yuan,&Wang, Li-Xin.(2015).Direct enantioselective amination of alpha-ketoester catalyzed by tertiary amine thiourea: a new approach to chiral alpha-hydroxy-beta-amino acid.Tetrahedron letters,56(28),4220-4223. |
| MLA | Fu, Ji-Ya,et al."Direct enantioselective amination of alpha-ketoester catalyzed by tertiary amine thiourea: a new approach to chiral alpha-hydroxy-beta-amino acid".Tetrahedron letters 56.28(2015):4220-4223. |
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来源：中国科学院大学
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