Metal complexes bearing 2-(imidazol-2-yl)phenol ligands: synthesis, characterization and catalytic performance in the fixation of carbon dioxide with epoxides
文献类型：期刊论文
| 作者 | Peng, Jing1; Yang, Hai-Jian2,3; Wei, Zidong1; Guo, Cun-Yue4 |
| 刊名 | Rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:65页码:53063-53072 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c5ra08237d |
| 通讯作者 | Yang, hai-jian(yanghaijian@vip.sina.com) |
| 英文摘要 | A series of metal complexes bearing 2-(imidazol-2-yl) phenol ligands (zn, cu, ni, co, pb) were synthesized and their structures were characterized by ir, nmr, elemental analysis and x-ray. the catalytic activities of all complexes for the coupling reaction of co2 and epoxide were then detected. the activity influence factors, such as temperature, time, pressure, substituents of ligands and metal centre, were systematically investigated. all these complexes were efficient to catalyze the coupling of co2 and epoxide to generate cyclic carbonate in perfect yields (>90%) and selectivities (>99%) under optimized conditions of (2 mpa, 5 h, 110 degrees c) without any organic solvents. a 99.7% yield and >99% selectivity for propylene carbonate (pc) were obtained with c-7/n-bu4ni as catalyst system under the optimized conditions. the catalysts were also proved to be applicable to other terminal epoxides. it is worthy noted that the pb(ii) complex was firstly used to catalyze the coupling reaction of epoxides with carbon dioxide. moreover, these metal catalysts were recyclable with only minor losses in catalytic activity after simple separation. finally, a plausible mechanism was given. |
| WOS关键词 | IONIC LIQUIDS EFFICIENT ; CYCLIC CARBONATES ; ORGANIC CARBONATES ; CO2 FIXATION ; STYRENE CARBONATE ; CYCLOHEXENE OXIDE ; PROPYLENE-OXIDE ; CYCLOADDITION ; SYSTEM ; GREEN |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000356462400091 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376485 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, Hai-Jian |
| 作者单位 | 1.Chongqing Univ, Coll Chem & Chem Engn, State Key Lab Power Transmission Equipment & Syst, Chongqing 400044, Peoples R China 2.South Cent Univ Nationalities, Key Lab Catalysis & Mat Sci State Ethn Affairs Co, Coll Chem & Mat Sci, Wuhan, Peoples R China 3.South Cent Univ Nationalities, Key Lab Analyt Chem State Ethn Affairs Commiss, Coll Chem & Mat Sci, Minist Educ, Wuhan, Peoples R China 4.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Jing,Yang, Hai-Jian,Wei, Zidong,et al. Metal complexes bearing 2-(imidazol-2-yl)phenol ligands: synthesis, characterization and catalytic performance in the fixation of carbon dioxide with epoxides[J]. Rsc advances,2015,5(65):53063-53072. |
| APA | Peng, Jing,Yang, Hai-Jian,Wei, Zidong,&Guo, Cun-Yue.(2015).Metal complexes bearing 2-(imidazol-2-yl)phenol ligands: synthesis, characterization and catalytic performance in the fixation of carbon dioxide with epoxides.Rsc advances,5(65),53063-53072. |
| MLA | Peng, Jing,et al."Metal complexes bearing 2-(imidazol-2-yl)phenol ligands: synthesis, characterization and catalytic performance in the fixation of carbon dioxide with epoxides".Rsc advances 5.65(2015):53063-53072. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。