Geometric and electronic structures of five-coordinate manganese(ii) "picket fence" porphyrin complexes
文献类型：期刊论文
| 作者 | Yu, Qiang1,2; Liu, Yanhong3; Liu, Diansheng1; Li, Jianfeng2 |
| 刊名 | Dalton transactions
 |
| 出版日期 | 2015 |
| 卷号 | 44期号:20页码:9382-9390 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c5dt00685f |
| 通讯作者 | Li, jianfeng() |
| 英文摘要 | Three five-coordinate, high spin manganese(ii) "picket fence" porphyrin complexes, [mn(tpivpp)(l)] (tpivpp = alpha,alpha,alpha,alpha-tetrakis(o-pivalamidophenyl)porphyrinato; l = 1-meim (1-methylimidazole), 1-etim (1-ethylimidazole) and 2-mehim (2-methylimidazole)), are synthesized and studied by single-crystal x-ray, uv-vis and electronic paramagnetic resonance (epr) spectroscopy. structural parameters are investigated and compared with analogues. low temperature (90 k), high field epr studies of [mn-(tpivpp)(1-meim)] and [mn(tpivpp)(2-mehim)] showed five resonances including characteristic signals at similar to 5.9 and similar to 2.0. the simulations of the epr spectra give the zero field splitting (zfs) parameters (d, e and lambda) and the hyperfine coupling constant (a). |
| WOS关键词 | OXYGEN-BINDING HEMOPROTEINS ; IX DIMETHYL ESTER ; HISTIDINE LINKAGE ; IRON PORPHYRINS ; LIGAND DYNAMICS ; DIOXYGEN ADDUCT ; SPIN-STATE ; HEMOGLOBIN ; RESONANCE ; CONFIGURATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000354999800011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376567 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Jianfeng |
| 作者单位 | 1.Shanxi Univ, Res Inst Appl Chem, Taiyuan 030006, Peoples R China 2.Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, Beijing 101408, Peoples R China 3.Tech Inst Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Qiang,Liu, Yanhong,Liu, Diansheng,et al. Geometric and electronic structures of five-coordinate manganese(ii) "picket fence" porphyrin complexes[J]. Dalton transactions,2015,44(20):9382-9390. |
| APA | Yu, Qiang,Liu, Yanhong,Liu, Diansheng,&Li, Jianfeng.(2015).Geometric and electronic structures of five-coordinate manganese(ii) "picket fence" porphyrin complexes.Dalton transactions,44(20),9382-9390. |
| MLA | Yu, Qiang,et al."Geometric and electronic structures of five-coordinate manganese(ii) "picket fence" porphyrin complexes".Dalton transactions 44.20(2015):9382-9390. |
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来源：中国科学院大学
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