Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses
文献类型：期刊论文
| 作者 | Zheng, Jun1,2; Wu, Mingyan1; Jiang, Feilong1; Su, Weiping1; Hong, Maochun1 |
| 刊名 | Chemical science
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:6页码:3466-3470 |
| ISSN号 | 2041-6520 |
| DOI | 10.1039/c5sc00213c |
| 通讯作者 | Wu, mingyan(wumy@fjirsm.ac.cn) |
| 英文摘要 | Two isostructural porphyrin zr and hf metal-organic frameworks (fji-h6 and fji-h7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed cu2+ ions into the open porphyrin rings. fji-h6 has a high bet surface area of 5033 m(2) g(-1). additionally, they exhibit promising catalytic abilities to convert co2 and epoxides into cyclic carbonates at ambient conditions. |
| WOS关键词 | GAS-STORAGE CAPACITIES ; WATER OXIDATION ; CO2 ADSORPTION ; STABILITY ; TOPOLOGY ; DERIVATIVES ; EFFICIENT ; HYDROGEN ; UIO-66 ; PHOTOCATALYSIS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000354815600026 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376571 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Mingyan |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Jun,Wu, Mingyan,Jiang, Feilong,et al. Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses[J]. Chemical science,2015,6(6):3466-3470. |
| APA | Zheng, Jun,Wu, Mingyan,Jiang, Feilong,Su, Weiping,&Hong, Maochun.(2015).Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses.Chemical science,6(6),3466-3470. |
| MLA | Zheng, Jun,et al."Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses".Chemical science 6.6(2015):3466-3470. |
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来源：中国科学院大学
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