Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde
文献类型：期刊论文
| 作者 | Gao, Peng1,2; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | catalysis letters
 |
| 出版日期 | 2008-10-01 |
| 卷号 | 125期号:3-4页码:289-295 |
| 关键词 | mesoporous carbon self-assembly ruthenium cinnamaldehyde cinnamyl alcohol hydrogenation |
| 产权排序 | 1;1 |
| 通讯作者 | 张涛 |
| 英文摘要 | highly ordered ru-containing mesoporous carbons (ru-omc) were for the first time synthesized by a one-pot method. comparing with our previously reported ir-omc, the ru precursor must be added after the formaldehyde was consumed by polycondensation with resorcinol to obtain a small particle size. the resultant ru-omc samples with different ru contents were characterized with x-ray diffraction (xrd), n(2) adsorption-desorption, and transmission electron microscopy (tem). the results evidenced the formation of highly ordered mesostructure, in which ru particles were imbedded. the new carbon materials were further evaluated in the selective hydrogenation of cinnamaldehyde (cma). by comparison with the traditional ru/ac catalyst, our ru-omc samples exhibited much higher activity (2-14-fold) and up to 60% of selectivity to cinnamyl alcohol (cmo). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | selective hydrogenation ; platinum nanoparticles ; molecular-sieve ; nanotubes ; frameworks ; capacity ; polymers ; alcohol ; storage ; route |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000259412500019 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/100829]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Peng,Wang, Aiqin,Wang, Xiaodong,et al. Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde[J]. catalysis letters,2008,125(3-4):289-295. |
| APA | Gao, Peng,Wang, Aiqin,Wang, Xiaodong,&Zhang, Tao.(2008).Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde.catalysis letters,125(3-4),289-295. |
| MLA | Gao, Peng,et al."Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde".catalysis letters 125.3-4(2008):289-295. |
入库方式： OAI收割
来源：大连化学物理研究所
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