中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde

文献类型:期刊论文

作者Gao, Peng1,2; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1
刊名catalysis letters
出版日期2008-10-01
卷号125期号:3-4页码:289-295
关键词mesoporous carbon self-assembly ruthenium cinnamaldehyde cinnamyl alcohol hydrogenation
产权排序1;1
通讯作者张涛
英文摘要highly ordered ru-containing mesoporous carbons (ru-omc) were for the first time synthesized by a one-pot method. comparing with our previously reported ir-omc, the ru precursor must be added after the formaldehyde was consumed by polycondensation with resorcinol to obtain a small particle size. the resultant ru-omc samples with different ru contents were characterized with x-ray diffraction (xrd), n(2) adsorption-desorption, and transmission electron microscopy (tem). the results evidenced the formation of highly ordered mesostructure, in which ru particles were imbedded. the new carbon materials were further evaluated in the selective hydrogenation of cinnamaldehyde (cma). by comparison with the traditional ru/ac catalyst, our ru-omc samples exhibited much higher activity (2-14-fold) and up to 60% of selectivity to cinnamyl alcohol (cmo).
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]selective hydrogenation ; platinum nanoparticles ; molecular-sieve ; nanotubes ; frameworks ; capacity ; polymers ; alcohol ; storage ; route
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000259412500019
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/100829]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Gao, Peng,Wang, Aiqin,Wang, Xiaodong,et al. Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde[J]. catalysis letters,2008,125(3-4):289-295.
APA Gao, Peng,Wang, Aiqin,Wang, Xiaodong,&Zhang, Tao.(2008).Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde.catalysis letters,125(3-4),289-295.
MLA Gao, Peng,et al."Synthesis and catalytic performance of highly ordered Ru-containing mesoporous carbons for hydrogenation of cinnamaldehyde".catalysis letters 125.3-4(2008):289-295.

入库方式: OAI收割

来源:大连化学物理研究所

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