An ionothermally synthesized mg-based coordination polymer as a precursor for preparing porous carbons
文献类型：期刊论文
| 作者 | Wu, Zhao-Feng1,2; Tan, Bin1,2; Du, Cheng-Feng1,2; Feng, Mei-Ling1; Xie, Zai-Lai3; Huang, Xiao-Ying1 |
| 刊名 | Crystengcomm
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:23页码:4288-4292 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/c5ce00591d |
| 通讯作者 | Wu, zhao-feng() |
| 英文摘要 | A new magnesium coordination polymer (mg-cp), namely [bmim](2)[mg-6(ndc)(5)(hndc)(2)(hcoo)(2)] (1, h2ndc = 1, 4-naphthalenedicarboxylic acid, [bmim] = 1-butyl-3-methyl-imidazolium ion), has been ionothermally synthesized and structurally characterized. single-crystal x-ray structural determination indicated that the title compound possessed an anionic three-dimensional (3d) framework constructed by the interconnections of unprecedented hexanuclear magnesium-carboxylate clusters as secondary building units (sbus) via bridging ndc ligands. compound 1 exhibited blue luminescence emission at 440 nm when excited at 360 nm. significantly, the title non-porous mg-cp could be utilized as a precursor for preparing porous carbons through thermal decomposition in optimized conditions. different from the reported high decomposition temperature (> 1000 degrees c) mostly based on porous zn-cp precursors, the optimum decomposition temperature for 1 was only 700 degrees c, and the resulting porous carbons showed 465 cm(3) g(-1) adsorption volume for n-2. the as-prepared carbon exhibited finely selective n-2 adsorption ability over h-2 and co2. this work may provide a certain guiding significance for exploiting ionothermally synthesized mg-cps as a new type of precursor towards porous carbons. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; NANOPOROUS CARBON ; IONIC LIQUIDS ; SURFACE-AREA ; MOF ; ADSORPTION ; FLUORESCENCE ; PERFORMANCE ; TEMPLATE ; NETWORK |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Multidisciplinary ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000355734400005 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376641 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Zhao-Feng |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Zhao-Feng,Tan, Bin,Du, Cheng-Feng,et al. An ionothermally synthesized mg-based coordination polymer as a precursor for preparing porous carbons[J]. Crystengcomm,2015,17(23):4288-4292. |
| APA | Wu, Zhao-Feng,Tan, Bin,Du, Cheng-Feng,Feng, Mei-Ling,Xie, Zai-Lai,&Huang, Xiao-Ying.(2015).An ionothermally synthesized mg-based coordination polymer as a precursor for preparing porous carbons.Crystengcomm,17(23),4288-4292. |
| MLA | Wu, Zhao-Feng,et al."An ionothermally synthesized mg-based coordination polymer as a precursor for preparing porous carbons".Crystengcomm 17.23(2015):4288-4292. |
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来源：中国科学院大学
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