Carbazole-based poly(aryl ether ketone) containing crosslinkable allyl groups on the side chains: synthesis, characterization and properties
文献类型：期刊论文
| 作者 | Wang, Feifei1,2; Wang, Zhipeng1,2; Wang, Honghua1; Zhou, Guangyuan1 |
| 刊名 | Polymer international
 |
| 出版日期 | 2015-07-01 |
| 卷号 | 64期号:7页码:858-866 |
| 关键词 | Poly(aryl ether ketone) Carbazole Allyl group Crosslinking reaction Solvent resistance Thermal stability Fluorescence |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.4857 |
| 通讯作者 | Zhou, guangyuan(gyzhou@ciac.ac.cn) |
| 英文摘要 | This paper presents a feasible method for introducing crosslinkable groups into a polymer to achieve excellent chemical resistance and improved thermal stability. here, 3,6-bi(4-fluorobenzenzoyl)-n-allylcarbazole, a novel allyl-containing difluoroketone monomer, is synthesized and characterized. the resulting monomer is polymerized with phenolphthalein through the aromatic nucleophilic substitution reaction at 160 degrees c to provide the soluble poly(aryl ether ketone) (paek) with a pendant allyl group. the obtained paek is characterized using fourier transform infrared spectroscopy, nmr and gel permeation chromatography. the crosslinking reaction of the polymer occurs at 270 degrees c, and it imparts excellent solvent resistance. dsc analysis shows that the glass transition temperature (t-g) of the cured polymer increases to 262-306 degrees c when the curing temperature is elevated or when the curing time is extended within certain limits. the rate of increase of t-g and the rate of the crosslinking reaction decrease as the curing time is extended under all of the investigated curing temperatures. the cured paeks possess good thermal stability with 5% weight loss temperatures up to 450 degrees c. the tensile strength and young's modulus of the polymer film cured at 300 degrees c for 2h are 65 mpa and 1.4 gpa, respectively. in addition, the polymer films before and after curing exhibit similar uv-visible absorption and blue light emission. (c) 2014 society of chemical industry |
| WOS关键词 | OPTICAL WAVE-GUIDES ; PHENYLETHYNYL MOIETIES ; ACTIVATED DIFLUORIDES ; COUPLING REACTIONS ; C-N ; POLYMERS ; POLYCARBAZOLES ; OLIGOMERS ; DEVICES ; PEEK |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000355633500002 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376680 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhou, Guangyuan |
| 作者单位 | 1.Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Feifei,Wang, Zhipeng,Wang, Honghua,et al. Carbazole-based poly(aryl ether ketone) containing crosslinkable allyl groups on the side chains: synthesis, characterization and properties[J]. Polymer international,2015,64(7):858-866. |
| APA | Wang, Feifei,Wang, Zhipeng,Wang, Honghua,&Zhou, Guangyuan.(2015).Carbazole-based poly(aryl ether ketone) containing crosslinkable allyl groups on the side chains: synthesis, characterization and properties.Polymer international,64(7),858-866. |
| MLA | Wang, Feifei,et al."Carbazole-based poly(aryl ether ketone) containing crosslinkable allyl groups on the side chains: synthesis, characterization and properties".Polymer international 64.7(2015):858-866. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。