Syntheses, structure, and magnetic properties of new 3d-4f heterometallic hydroxysulfates ln(2)cu(so4)(2)(oh)(4) (ln = sm, eu, tb, or dy) with a two-dimensional triangle network
文献类型：期刊论文
| 作者 | Tang, Yingying1,3; Cui, Meiyan1,3; Guo, Wenbin1; Zhang, Suyun1; Yang, Ming1; He, Zhangzhen1,2 |
| 刊名 | Crystal growth & design
 |
| 出版日期 | 2015-06-01 |
| 卷号 | 15期号:6页码:2742-2747 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/acs.cgd.5b00057 |
| 通讯作者 | He, zhangzhen(hcz1988@hotmail.com) |
| 英文摘要 | A series of 3d-4f hydroxysulfates, ln(2)cu-(so4)(2)(oh)(4) (ln = sm, eu, tb, or dy) have been successfully obtained by the conventional hydrothermal method. these compounds crystallize in the monoclinic system in space group p2(1)/c, showing a layered structure. the layers are built by the lno(9) polyhedra and cuo4 planar squares, which are separated by so42 tetrahedra. the topological structure of sm3+ ions shows a distorted honeycomb lattice, while cu2+ ions ate located at the,center of a honeycomb framework forming a triangle lattice, magnetic measurements reveal that the isostructural ln(2)cu(so4)(2)(oh)(4) exhibits different magnetic behaviors at low temperatures, which may be attributed to the different contribution of 3d-4f coupling. |
| WOS关键词 | COBALT HYDROXYSULFATES ; LANTHANIDE ; CRYSTAL ; SULFATE ; OXIDES ; CHAINS ; LU ; YB ; ER ; TM |
| WOS研究方向 | Chemistry ; Crystallography ; Materials Science |
| WOS类目 | Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000355890400025 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376754 |
| 专题 | 中国科学院大学 |
| 通讯作者 | He, Zhangzhen |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Yingying,Cui, Meiyan,Guo, Wenbin,et al. Syntheses, structure, and magnetic properties of new 3d-4f heterometallic hydroxysulfates ln(2)cu(so4)(2)(oh)(4) (ln = sm, eu, tb, or dy) with a two-dimensional triangle network[J]. Crystal growth & design,2015,15(6):2742-2747. |
| APA | Tang, Yingying,Cui, Meiyan,Guo, Wenbin,Zhang, Suyun,Yang, Ming,&He, Zhangzhen.(2015).Syntheses, structure, and magnetic properties of new 3d-4f heterometallic hydroxysulfates ln(2)cu(so4)(2)(oh)(4) (ln = sm, eu, tb, or dy) with a two-dimensional triangle network.Crystal growth & design,15(6),2742-2747. |
| MLA | Tang, Yingying,et al."Syntheses, structure, and magnetic properties of new 3d-4f heterometallic hydroxysulfates ln(2)cu(so4)(2)(oh)(4) (ln = sm, eu, tb, or dy) with a two-dimensional triangle network".Crystal growth & design 15.6(2015):2742-2747. |
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来源：中国科学院大学
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