Understanding the formation mechanism of graphene frameworks synthesized by solvothermal and rapid pyrolytic processes based on an alcohol-sodium hydroxide system
文献类型：期刊论文
| 作者 | Cui, Huijuan1,2; Zheng, Jianfeng1; Yang, Pengju1,2; Zhu, Yanyan1,2; Wang, Zhijian1; Zhu, Zhenping1 |
| 刊名 | Acs applied materials & interfaces
 |
| 出版日期 | 2015-06-03 |
| 卷号 | 7期号:21页码:11230-11238 |
| 关键词 | Graphene Alcohol-sodium Formation mechanism Solvothermal Pyrolysis |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.5b01201 |
| 通讯作者 | Zheng, jianfeng(zhengjf@sxicc.ac.cn) |
| 英文摘要 | The determination of ways to facilitate the 2d-oriented assembly of carbons into graphene instead of other carbon structures while restraining the pi-pi stacking interaction is a challenge for the controllable bulk synthesis of graphene, which is vital both scientifically and technically. in this study, graphene frameworks (gfs) are synthesized by solvothermal and rapid pyrolytic processes based on an alcohol-sodium hydroxide system. the evolution mechanism of gfs is investigated systematically. under sodium catalysis, the abundant carbon atoms produced by the fast decomposition of solvothermal intermediate self-assembled to graphene. the existence of abundant ether bonds may be favorable for 3d graphene formation. more importantly, gfs were successfully obtained using acetic acid as the carbon source in the synthetic process, suggesting the reasonability of analyzing the formation mechanism. it is quite possible to determine more favorable routes to synthesize graphene under this cognition. the electrochemical energy storage capacity of gfs was also studied, which revealed a high supercapacitor performance with a specific capacitance of 310.7 f/g at the current density of 0.2 a/g. |
| WOS关键词 | CAPACITIVE ENERGY-STORAGE ; LAYER GRAPHENE ; GRAPHITE OXIDE ; REDUCTION ; COMBUSTION ; NMR |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000355891700023 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376762 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zheng, Jianfeng |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Univ Chinese Acad Sci, Beijing 010049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Huijuan,Zheng, Jianfeng,Yang, Pengju,et al. Understanding the formation mechanism of graphene frameworks synthesized by solvothermal and rapid pyrolytic processes based on an alcohol-sodium hydroxide system[J]. Acs applied materials & interfaces,2015,7(21):11230-11238. |
| APA | Cui, Huijuan,Zheng, Jianfeng,Yang, Pengju,Zhu, Yanyan,Wang, Zhijian,&Zhu, Zhenping.(2015).Understanding the formation mechanism of graphene frameworks synthesized by solvothermal and rapid pyrolytic processes based on an alcohol-sodium hydroxide system.Acs applied materials & interfaces,7(21),11230-11238. |
| MLA | Cui, Huijuan,et al."Understanding the formation mechanism of graphene frameworks synthesized by solvothermal and rapid pyrolytic processes based on an alcohol-sodium hydroxide system".Acs applied materials & interfaces 7.21(2015):11230-11238. |
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来源：中国科学院大学
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