Chemical stability and tunable luminescence of ln(iii)-k(i) coordination polymers featuring a tracery-like architecture
文献类型：期刊论文
| 作者 | Li, Qipeng1,3; Yuan, Zeli2; Qian, Jinjie1,3; Du, Shaowu1 |
| 刊名 | Rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:61页码:49110-49114 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c5ra07602a |
| 通讯作者 | Du, shaowu(swdu@ffirsm.ac.cn) |
| 英文摘要 | With the help of in situ generation of a sulfate anion, three heterometallic ln(iii)-k(i) sulfate and oxalate coordination polymers, formulated as [kln(ox)(so4)(h2o)] (ox = oxalate, ln = eu 1, tb 2 and dy 3) have been successfully synthesized and structurally characterized. they are isomorphic and each displays a tracery-like structure inlaid with two different kinds of hexagons. in addition, compound 2 is thermally stable up to 350 degrees c and exhibits unusual chemical stability in a wide ph range of 0-12, as confirmed by the variable temperature xrd and ph dependent xrd. tunable luminescence of 2 is achieved by changing the temperature and ph, which indicates that it can be potentially used as a probe for sensing temperature and ph. |
| WOS关键词 | METAL-ORGANIC FRAMEWORK ; SLOW MAGNETIC-RELAXATION ; HIGH THERMAL-STABILITY ; HIGHLY LUMINESCENT ; 3D ; EMISSION ; LIGANDS ; SULFATE ; MOFS ; PHOTOLUMINESCENCE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000355989400011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376765 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Du, Shaowu |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Zunyi Med Univ, Sch Pharm, Zunyi 563003, Guizhou, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Qipeng,Yuan, Zeli,Qian, Jinjie,et al. Chemical stability and tunable luminescence of ln(iii)-k(i) coordination polymers featuring a tracery-like architecture[J]. Rsc advances,2015,5(61):49110-49114. |
| APA | Li, Qipeng,Yuan, Zeli,Qian, Jinjie,&Du, Shaowu.(2015).Chemical stability and tunable luminescence of ln(iii)-k(i) coordination polymers featuring a tracery-like architecture.Rsc advances,5(61),49110-49114. |
| MLA | Li, Qipeng,et al."Chemical stability and tunable luminescence of ln(iii)-k(i) coordination polymers featuring a tracery-like architecture".Rsc advances 5.61(2015):49110-49114. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。