Chemical fixation of co2 with highly efficient zncl2/[bmim]br catalyst system
文献类型:期刊论文
作者 | Li, FW; Xiao, LF; Xia, CG; Hu, B |
刊名 | Tetrahedron letters
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出版日期 | 2004-11-01 |
卷号 | 45期号:45页码:8307-8310 |
关键词 | Chemical fixation of co2 Epoxide Zncl2/[bmim]br Catalyst reused Pure cis-cyclic carbonate of cyclohexene oxide |
ISSN号 | 0040-4039 |
DOI | 10.1016/j.tetlet.2004.09.074 |
通讯作者 | Xia, cg() |
英文摘要 | The chemical fixation of co2 with mono-substituted terminal epoxides or cyclohexene oxide to form cyclic carbonates under the zncl2/[bmim]br catalyst system without using additional organic solvents was achieved in excellent selectivity (>98%) and tof (5410 h(-1)) and the catalyst could be used six times almost without losing its catalytic activity and selectivity. besides, the pure cis-cyclic carbonate of cyclohexene oxide was obtained in this catalyst system. (c) 2004 elsevier ltd. all rights reserved. |
WOS关键词 | CARBON-DIOXIDE ; COUPLING REACTIONS ; PROPYLENE-OXIDE ; IONIC LIQUIDS ; EPOXIDES ; COMPLEXES ; CYCLOADDITION |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
WOS记录号 | WOS:000224632600009 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376930 |
专题 | 中国科学院大学 |
通讯作者 | Xia, CG |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Li, FW,Xiao, LF,Xia, CG,et al. Chemical fixation of co2 with highly efficient zncl2/[bmim]br catalyst system[J]. Tetrahedron letters,2004,45(45):8307-8310. |
APA | Li, FW,Xiao, LF,Xia, CG,&Hu, B.(2004).Chemical fixation of co2 with highly efficient zncl2/[bmim]br catalyst system.Tetrahedron letters,45(45),8307-8310. |
MLA | Li, FW,et al."Chemical fixation of co2 with highly efficient zncl2/[bmim]br catalyst system".Tetrahedron letters 45.45(2004):8307-8310. |
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来源:中国科学院大学
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