Zirconium phosphate/Nafion115 composite membrane for high-concentration DMFC
文献类型：期刊论文
| 作者 | Hou, Hongying1,3; Sun, Gongquan1; Wu, Zhimou1,3; Jin, Wei1,3; Xin, Qin1,2 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2008-07-01 |
| 卷号 | 33期号:13页码:3402-3409 |
| 关键词 | ZrP/Nafion115 methanol crossover DMFC durability |
| 产权排序 | 1;1 |
| 通讯作者 | 孙公权 |
| 英文摘要 | zirconium phosphate/nafion115 (zrp/nafion115) composite membrane was prepared. it was characterized by means of xrd, edx, ion-exchange capacity (iec), thermogravimetry analysis (tga) and so on. the results suggested that the mean particle size of zirconium phosphate within the composite membrane was about 5.0 nm. the composite membrane had comparable thermal stability with nafion115, and its iec markedly increased. the methanol crossover through it decreased by about 50% compared with that through nafion115, while the proton conductivity slightly decreased. the single performance tests demonstrated that the use of composite membrane reduced mass transport polarization, thus resulting in better cell performance at 75 degrees c with higher methanol concentration (10m) as fuel. the preliminary result of durability test showed that the single cell with composite membrane can stably run 100h above 0.4v. (c) 2008 international association for hydrogen energy. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | methanol fuel-cell ; ion-exchange ; phosphate ; crossover ; operation ; nafion(r) ; crystallinity ; temperature |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000258518000017 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/100889]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cells Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hou, Hongying,Sun, Gongquan,Wu, Zhimou,et al. Zirconium phosphate/Nafion115 composite membrane for high-concentration DMFC[J]. international journal of hydrogen energy,2008,33(13):3402-3409. |
| APA | Hou, Hongying,Sun, Gongquan,Wu, Zhimou,Jin, Wei,&Xin, Qin.(2008).Zirconium phosphate/Nafion115 composite membrane for high-concentration DMFC.international journal of hydrogen energy,33(13),3402-3409. |
| MLA | Hou, Hongying,et al."Zirconium phosphate/Nafion115 composite membrane for high-concentration DMFC".international journal of hydrogen energy 33.13(2008):3402-3409. |
入库方式： OAI收割
来源：大连化学物理研究所
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