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Synthesis and properties of polyimides from isomeric bis(dicarboxylphenylthio)diphenyl sulfone dianhydrides

文献类型:期刊论文

作者Yan, JL; Wang, Z; Gao, LX; Ding, MX
刊名Polymer
出版日期2005-08-23
卷号46期号:18页码:7678-7683
关键词Ptpsda Isomeric polyimides Structure-property relations
ISSN号0032-3861
DOI10.1016/j.polymer.2005.05.157
通讯作者Ding, mx()
英文摘要4,4'-bis(3,4-dicarboxyphenylthio)diphenyl sulfone dianhydride(4,4'-ptpsda) and 4,4'-bis(2,3-dicarboxyphenylthio)diphenyl sulfone dianhydride(3,3'-ptpsda) were synthesized from chlorophthalic anhydrides and bis(4-mercaptophenyl)sulfone. their structures were determined via ir spectra, h-1 nmr and elemental analysis. a series of polyimides were prepared from isomeric ptpsdas and aromatic diamines in 1-methyl-2-pyrrolidinone (nmp) via the conventional two-step method. polyimides based on 4,4'-ptpsda and 3.3'-ptpsda have good solubility in polar aprotic solvents and phenols. the 5% weight-loss temperatures of isomeric polyimides were near 500 degrees c in n-2. dmta and dsc analyses indicated that the glass-transition temperatures of polyimides front 3,3'-ptpsda are higher than those of polyimides from 4,4'-ptpsda. the wide-angle x-ray diffraction showed that all polyimides are amorphous. the polyimides from 3,3'ptpsda showed higher permeability but lower permselectivity compared with those from 4.4'-ptpsda. (c) 2005 elsevier ltd. all rights reserved.
WOS关键词THIAPHTHALIC DIANHYDRIDE ; SOLUBLE POLYIMIDES ; THIOPHENOXIDES ; OXYDIANILINE ; DIAMINE
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000231397200098
出版者ELSEVIER SCI LTD
URI标识http://www.irgrid.ac.cn/handle/1471x/2377009
专题中国科学院大学
通讯作者Ding, MX
作者单位Chinese Acad Sci, Grad Sch, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Yan, JL,Wang, Z,Gao, LX,et al. Synthesis and properties of polyimides from isomeric bis(dicarboxylphenylthio)diphenyl sulfone dianhydrides[J]. Polymer,2005,46(18):7678-7683.
APA Yan, JL,Wang, Z,Gao, LX,&Ding, MX.(2005).Synthesis and properties of polyimides from isomeric bis(dicarboxylphenylthio)diphenyl sulfone dianhydrides.Polymer,46(18),7678-7683.
MLA Yan, JL,et al."Synthesis and properties of polyimides from isomeric bis(dicarboxylphenylthio)diphenyl sulfone dianhydrides".Polymer 46.18(2005):7678-7683.

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来源:中国科学院大学

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