中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent

文献类型:期刊论文

作者Ma, JR; Huang, ZG; Liu, ZY; Guo, SJ
刊名Chinese journal of catalysis
出版日期2005-06-01
卷号26期号:6页码:463-469
关键词Vanadium pentoxide Activated carbon Sulfur dioxide Nitric oxide Removal Water-washing Catalyst regeneration Ammonia
ISSN号0253-9837
通讯作者Liu, zy()
英文摘要The regeneration of a used v2o5 /ac catalyst-sorbent, which is active for simultaneous removal of so2 and no from flue gas, was studied using different methods. water-washing caused the loss of a considerable amount of v from the catalyst surface and consequently could not rejuvenate the initial activity of the catalyst. thermal regeneration by ar showed better results, but the activity for so2 removal could not be fully recovered due to the presence of residue sulfur and the loss of carbon in the catalyst. reductive regeneration by 5% nh3-95% ar displayed the best results, the so2 removal activity could be completely revived and the no removal activity improved greatly. the results of ir and xps showed that a large amount of nitrogen function groups, nh4+/nh2-, were formed and enhanced the no removal activity. ammonia could also react with the formed so2 to produce ammonium sulfite at the reactor outlet, which simplified the post-treatment process.
WOS关键词LOW-TEMPERATURE ; REDUCTION ; AMMONIA ; GAS ; DESULFURIZATION ; ADSORPTION ; NH3
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
语种英语
WOS记录号WOS:000230445000009
出版者SCIENCE PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2377036
专题中国科学院大学
通讯作者Liu, ZY
作者单位1.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Shanxi, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Ma, JR,Huang, ZG,Liu, ZY,et al. Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent[J]. Chinese journal of catalysis,2005,26(6):463-469.
APA Ma, JR,Huang, ZG,Liu, ZY,&Guo, SJ.(2005).Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent.Chinese journal of catalysis,26(6),463-469.
MLA Ma, JR,et al."Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent".Chinese journal of catalysis 26.6(2005):463-469.

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来源:中国科学院大学

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