Syntheses, crystal structures and characterization of a series of heterothiometallic gold(i) complexes containing bridging diphosphine ligands
文献类型：期刊论文
| 作者 | Song, L; Xia, SQ; Hu, SM; Du, SW; Wu, XT |
| 刊名 | Polyhedron
 |
| 出版日期 | 2005-05-12 |
| 卷号 | 24期号:7页码:831-836 |
| 关键词 | Heterothiometalates Gold Luminescence Diphosphine Crystal structure |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2005.02.021 |
| 通讯作者 | Du, sw() |
| 英文摘要 | A series of tetranuclear heterothiometallic clusters [et4n](2)[(ms4)(2)au-2(dppe)] (1: m = mo; 2: m = w), [pph4](2)[(moos3)(2)au-2(dppe)] (3), [et4n](2)[(wos3)(2)au-2(dppe)] (4) (dppe = 1,2-bis(diphenylphosphino)ethane), [et4n](2)[(ms4)(2)au-2(dppf)] (5: m = mo; 6: m = w) and [et4n](2)[(mos3)(2)au-2(dppf)] (7: m = mo; 8: m = w) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) have been synthesized from the reactions of thiometalates [mxs3](2-) (m = mo or w, x = o or s), aucl(sc4h8) and dppe or dppf. the crystal structures of the complexes 2, 4 and 6 have been determined by single-crystal x-ray diffraction studies. in the molecular structures of these complexes, the two linear m/au/s units are linked via bidentate phosphines dppe or dppf. the complexes have been fully characterized by ir, uv-vis as well as elemental analyses. these clusters all exhibit room-temperature luminescence in the solid state. © 2005 elsevier ltd. all rights reserved. |
| WOS关键词 | CLUSTER COMPOUNDS ; SULFUR CLUSTERS ; METAL-CLUSTERS ; THIOMOLYBDATES ; NITROGENASE ; BIOLOGY |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000229164100008 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377075 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Du, SW |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, L,Xia, SQ,Hu, SM,et al. Syntheses, crystal structures and characterization of a series of heterothiometallic gold(i) complexes containing bridging diphosphine ligands[J]. Polyhedron,2005,24(7):831-836. |
| APA | Song, L,Xia, SQ,Hu, SM,Du, SW,&Wu, XT.(2005).Syntheses, crystal structures and characterization of a series of heterothiometallic gold(i) complexes containing bridging diphosphine ligands.Polyhedron,24(7),831-836. |
| MLA | Song, L,et al."Syntheses, crystal structures and characterization of a series of heterothiometallic gold(i) complexes containing bridging diphosphine ligands".Polyhedron 24.7(2005):831-836. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。