Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system
文献类型：期刊论文
| 作者 | Yang, Z; Li, J; Yang, XG; Wu, Y |
| 刊名 | Catalysis letters
 |
| 出版日期 | 2005-04-01 |
| 卷号 | 100期号:3-4页码:205-211 |
| 关键词 | Formaldehyde Methanol Methyl formate Oxygen species Silver Synergic effect |
| ISSN号 | 1011-372X |
| DOI | 10.1007/s10562-004-3457-2 |
| 通讯作者 | Yang, xg() |
| 英文摘要 | Catalytic reaction was performed in the unregarded temperature region over silver catalysts with long catalytic lifetime for the conversion of methanol to methyl formate. o-alpha-saturated or o-gamma-saturated silver catalysts were studied individually to identify the roles of o-alpha, o-gamma in the oxidative esterification of methanol over an unsupported polycrystalline silver catalyst. a synergic process is proposed based on the coexistence of alpha-oxygen species and gamma-oxygen species on the surface of polycrystalline silver at about 573 k. |
| WOS关键词 | IN-SITU RAMAN ; SELECTIVE OXIDATION ; POLYCRYSTALLINE SILVER ; ELECTROLYTIC SILVER ; SUBSURFACE OXYGEN ; FORMALDEHYDE ; DEHYDROGENATION ; MECHANISM ; ETHYLENE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000228226800015 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377101 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, XG |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Lab Mat & Devices, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Z,Li, J,Yang, XG,et al. Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system[J]. Catalysis letters,2005,100(3-4):205-211. |
| APA | Yang, Z,Li, J,Yang, XG,&Wu, Y.(2005).Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system.Catalysis letters,100(3-4),205-211. |
| MLA | Yang, Z,et al."Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system".Catalysis letters 100.3-4(2005):205-211. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。