The reaction mechanism for the synthesis of 1-methoxy-2-propanol on mgo catalyst
文献类型：期刊论文
| 作者 | Zhang, WY; Dong, QN; Zhao, N; Wei, W; Sun, YH |
| 刊名 | Acta physico-chimica sinica
 |
| 出版日期 | 2005-06-01 |
| 卷号 | 21期号:6页码:653-657 |
| 关键词 | Methanol Poropylene oxide Ir 1-methoxy-2-propanol Mgo |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/pku.whxb20050615 |
| 通讯作者 | Sun, yh(yhsun@sxicc.ac.cn) |
| 英文摘要 | The addition of propylene oxide with methanol was carried out over mgo and a detailed mechanism of the reaction was investigated by using ft-ir method. in-situ ftir revealed that methanol dissociation into methoxide and proton took place readily on mgo, and propylene oxide adsorbed on mgo could generate propylene-like species via carbanion intermediate. as a result, methanol dissociated into adsorbed methoxide and reacted with the propylene-like species in anti-markownikov fashion, which led to the high selectivity to 1-methoxy-2propanol on mgo. |
| WOS关键词 | MAGNESIUM-OXIDE ; METHANOL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000230129500015 |
| 出版者 | PEKING UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377121 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Sun, YH |
| 作者单位 | 1.Chinese Acad Sci, Shanxi Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, WY,Dong, QN,Zhao, N,et al. The reaction mechanism for the synthesis of 1-methoxy-2-propanol on mgo catalyst[J]. Acta physico-chimica sinica,2005,21(6):653-657. |
| APA | Zhang, WY,Dong, QN,Zhao, N,Wei, W,&Sun, YH.(2005).The reaction mechanism for the synthesis of 1-methoxy-2-propanol on mgo catalyst.Acta physico-chimica sinica,21(6),653-657. |
| MLA | Zhang, WY,et al."The reaction mechanism for the synthesis of 1-methoxy-2-propanol on mgo catalyst".Acta physico-chimica sinica 21.6(2005):653-657. |
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来源：中国科学院大学
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