Syntheses, structures and characterization of heterobimetallic compounds [et4n](2)[(ms4)ag-8(sbut)(8)] (m = w, mo) and {[et4n][wos3ag2(s2coet)]}(n)
文献类型：期刊论文
| 作者 | Li, JR; Li, ZH; Du, SW; Wu, XT |
| 刊名 | Polyhedron
 |
| 出版日期 | 2005-03-10 |
| 卷号 | 24期号:4页码:481-485 |
| 关键词 | Tetrathiotungstate Tetrathiomolybdate Silver (i) compounds W/ag/s polymer Crystal structure Monocyclic silver alkanethiolates |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2004.12.011 |
| 通讯作者 | Du, sw() |
| 英文摘要 | Three new m/ag/s heterobimetallic compounds [et4n](2)[(ms4)ag-8(sbut)(8)] (1a, m = w; 1b, m = mo) and {[et4n][wos3ag2-(s2coet)]}(n) (2) have been prepared from the reactions of [mons4-n](2-) (m = w, mo; n = 0-1) with agsbut or ags2coet. single crystal structural studies show that the compound la contains a [ws4](2-) dianion encapsulated in a neutral octanuclear (agsbut)(8) cage via weak (ags)-s-...(ws4) interactions. in compound 2, butterfly wos3ag2 fragments are connected via bidentate bridging [s2coet](-) ligands to give a chain polymeric anion. these compounds are fully characterized by ir, uv-vis and microanalyses. compound 2 is the first w/ag/s polymer with bidentate thiolato linkages. (c) 2005 elsevier ltd. all rights reserved. |
| WOS关键词 | HINDERED THIOLATE LIGANDS ; MOLECULAR-STRUCTURES ; CRYSTAL-STRUCTURE ; ELECTRICAL-PROPERTIES ; CLUSTER COMPOUNDS ; COMPLEXES ; CHEMISTRY ; CHAIN ; COORDINATION ; SILVER(I) |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000227571000003 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377239 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Du, SW |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, JR,Li, ZH,Du, SW,et al. Syntheses, structures and characterization of heterobimetallic compounds [et4n](2)[(ms4)ag-8(sbut)(8)] (m = w, mo) and {[et4n][wos3ag2(s2coet)]}(n)[J]. Polyhedron,2005,24(4):481-485. |
| APA | Li, JR,Li, ZH,Du, SW,&Wu, XT.(2005).Syntheses, structures and characterization of heterobimetallic compounds [et4n](2)[(ms4)ag-8(sbut)(8)] (m = w, mo) and {[et4n][wos3ag2(s2coet)]}(n).Polyhedron,24(4),481-485. |
| MLA | Li, JR,et al."Syntheses, structures and characterization of heterobimetallic compounds [et4n](2)[(ms4)ag-8(sbut)(8)] (m = w, mo) and {[et4n][wos3ag2(s2coet)]}(n)".Polyhedron 24.4(2005):481-485. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。