Synthesis and crystal structure of a 3-d hydrogen-bonded supramolecular decavanadate compound [habo](6)[v10o28]center dot 2c(3)h(7)oh center dot 2h(2)o
文献类型:期刊论文
作者 | Chen, L; Lin, ZZ; Jiang, FL; Yuan, DQ; Hong, MC |
刊名 | Chinese journal of structural chemistry
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出版日期 | 2005 |
卷号 | 24期号:10页码:1186-1192 |
关键词 | Decavanadate Hydrogen bond Three-dimensional Crystal structure |
ISSN号 | 0254-5861 |
通讯作者 | Jiang, fl() |
英文摘要 | A new inorganic-organic hybrid supramolecular compound [habo](6)[v10o28](.)2c(3)h(7)oh-2h(2)o i (abo = r(-)-2-amino-1-butanol) has been synthesized from vo2+ in organic solvents and its crystal structure was reported as follows: monoclinic, space group p21/n, a = 11.419(9), b = 16.811(16), c = 15.521(12) angstrom, beta = 102.98(2)degrees, v = 2903(4) angstrom(3), z = 4, c15h46n3o19v5, m-r = 827.25, d-c = 1.893 g/cm(3), lambda(mok alpha) = 0.71073 angstrom, mu = 1.636 mm(-1), f(000) = 1696, the final r = 0.0696 and wr = 0.1361 for 4641 observed reflections with i > 2 sigma(i). the compound is based on decavanadate clusters [v10o28](6-). the hydrogen bonding interactions among habo(+) cations, solvents and decavanadate clusters extend i into a three-dimensional supramolecular architecture. |
WOS关键词 | THERMAL-BEHAVIOR |
WOS研究方向 | Chemistry ; Crystallography |
WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
语种 | 英语 |
WOS记录号 | WOS:000232871500015 |
出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377248 |
专题 | 中国科学院大学 |
通讯作者 | Jiang, FL |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, L,Lin, ZZ,Jiang, FL,et al. Synthesis and crystal structure of a 3-d hydrogen-bonded supramolecular decavanadate compound [habo](6)[v10o28]center dot 2c(3)h(7)oh center dot 2h(2)o[J]. Chinese journal of structural chemistry,2005,24(10):1186-1192. |
APA | Chen, L,Lin, ZZ,Jiang, FL,Yuan, DQ,&Hong, MC.(2005).Synthesis and crystal structure of a 3-d hydrogen-bonded supramolecular decavanadate compound [habo](6)[v10o28]center dot 2c(3)h(7)oh center dot 2h(2)o.Chinese journal of structural chemistry,24(10),1186-1192. |
MLA | Chen, L,et al."Synthesis and crystal structure of a 3-d hydrogen-bonded supramolecular decavanadate compound [habo](6)[v10o28]center dot 2c(3)h(7)oh center dot 2h(2)o".Chinese journal of structural chemistry 24.10(2005):1186-1192. |
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来源:中国科学院大学
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