In situ synthesis of pt nanoparticles in hyperbranched thin film for electrocatalytic reduction of dioxygen
文献类型：期刊论文
| 作者 | Liu, YQ; Yang, ML; Zheng, ZK; Zhang, BL |
| 刊名 | Electrochimica acta
 |
| 出版日期 | 2005-11-01 |
| 卷号 | 51期号:4页码:605-610 |
| 关键词 | Hyperbranched thin film In situ synthesis Pt nanoparticles Electrocatalytic reduction Dioxygen |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2005.05.020 |
| 通讯作者 | Zhang, bl() |
| 英文摘要 | Hyperbranched thin film (htf) with amino and imino groups, which can accommodate ptcl62-, was synthesized with small organic molecules on gold substrate based on sn2 displacement reaction. platinum nanoparticles (pt-nps) were in situ synthesized by electrochemically reduction of precursors, ptcl62-, within htf. the prepared films were characterized by x-ray photoelectron spectroscopy (xps), electrochemical impedance spectroscopy (eis) and atomic force microscopy (afm). it was confirmed that densely packed pt-nps were prepared with a narrow size distribution. eis indicated that htf inhibits electron transfer slightly while pt nanoparticles in the htf enhanced the electron-transfer ability greatly. cyclic voltammetry (cv) indicated that htf containing pt-nps exhibited a remarkable electrocatalytic activity for the electrochemical reduction of dioxygen. the quantity of pt-nps could be expediently controlled by the thickness of htf. so the catalytic ability can be tailored correspondingly. (c) 2005 elsevier ltd. all rights reserved. |
| WOS关键词 | SELF-ASSEMBLED MONOLAYERS ; GLASSY-CARBON ELECTRODE ; OXYGEN REDUCTION ; QUANTUM DOTS ; NANOCLUSTERS ; DENDRIMERS ; CHEMISTRY ; METAL ; CONSTRUCTION ; MULTILAYERS |
| WOS研究方向 | Electrochemistry |
| WOS类目 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000233298600004 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377251 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, BL |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanal Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, YQ,Yang, ML,Zheng, ZK,et al. In situ synthesis of pt nanoparticles in hyperbranched thin film for electrocatalytic reduction of dioxygen[J]. Electrochimica acta,2005,51(4):605-610. |
| APA | Liu, YQ,Yang, ML,Zheng, ZK,&Zhang, BL.(2005).In situ synthesis of pt nanoparticles in hyperbranched thin film for electrocatalytic reduction of dioxygen.Electrochimica acta,51(4),605-610. |
| MLA | Liu, YQ,et al."In situ synthesis of pt nanoparticles in hyperbranched thin film for electrocatalytic reduction of dioxygen".Electrochimica acta 51.4(2005):605-610. |
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来源：中国科学院大学
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