Low-temperature flux synthesis, crystal structure and ce-doped luminescence of the first lutetium diphosphate nh4lup2o7
文献类型：期刊论文
| 作者 | Li, MR; Liu, W; Chen, HH; Yang, XX; Wei, ZB; Cao, DH; Gu, M; Zhao, JT |
| 刊名 | European journal of inorganic chemistry
 |
| 出版日期 | 2005-12-02 |
| 期号 | 23页码:4693-4696 |
| 关键词 | Low-temperature self-flux synthesis Structure Diphosphate Luminescence |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200500477 |
| 通讯作者 | Zhao, jt(jtzhao@mail.sic.ac.cn) |
| 英文摘要 | The first lutetium diphosphate nh4lup2o7 has been prepared by a two-step, low-temperature self-flux synthesis in the presence of the f-anion, functioning as a mineralizer, which played a significant role in the synthetic process. the crystal structure has been characterized by single-crystal xray diffraction. the title compound crystallizes in a monoclinic system of the space group p2(1)/c (no. 14), a = 7.651(2) angstrom, b = 10.789(2) angstrom, c = 8.577(2) angstrom, beta = 105.75(3)degrees, v = 681.4(2) angstrom(3), z = 4, the three-dimensional framework of nh4lup2o7, composed of lu2p4o14 building units formed by vertex-linking luo6 and p2o7 goups, is isostructural with compounds of the type kaip(2)o(7) in the ternary diphosphate(a(i)m(iii)p(2)o(7)) system. x-ray-excited luminescence measurements of ce-activated samples show insteresting scintillation properties with a short decay time of 16 ns at room temperature. ((c) wiley-vch verlag gmbh & co. kgaa, 69451 weinheim, germany, 2005). |
| WOS关键词 | BOND-VALENCE PARAMETERS ; NAFEP2O7 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000233896500002 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377286 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhao, JT |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China 3.Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China 4.Tongji Univ, Dept Phys, Shanghai 200020, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, MR,Liu, W,Chen, HH,et al. Low-temperature flux synthesis, crystal structure and ce-doped luminescence of the first lutetium diphosphate nh4lup2o7[J]. European journal of inorganic chemistry,2005(23):4693-4696. |
| APA | Li, MR.,Liu, W.,Chen, HH.,Yang, XX.,Wei, ZB.,...&Zhao, JT.(2005).Low-temperature flux synthesis, crystal structure and ce-doped luminescence of the first lutetium diphosphate nh4lup2o7.European journal of inorganic chemistry(23),4693-4696. |
| MLA | Li, MR,et al."Low-temperature flux synthesis, crystal structure and ce-doped luminescence of the first lutetium diphosphate nh4lup2o7".European journal of inorganic chemistry .23(2005):4693-4696. |
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来源：中国科学院大学
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